4-Bromoanisole

4-Bromoanisole Structure
4-Bromoanisole structure
Common Name 4-Bromoanisole
CAS Number 104-92-7 Molecular Weight 187.034
Density 1.4±0.1 g/cm3 Boiling Point 223.0±0.0 °C at 760 mmHg
Molecular Formula C7H7BrO Melting Point 9-10 °C(lit.)
MSDS Chinese USA Flash Point 94.4±0.0 °C

Contributions of BrCl, Br2, BrOCl, Br2O, and HOBr to regiospecific bromination rates of anisole and bromoanisoles in aqueous solution.

Environ. Sci. Technol. 49(8) , 4937-45, (2015)

When bromide-containing waters are chlorinated, conventional wisdom typically assumes HOBr is the only active brominating agent. Several additional and often-overlooked brominating agents (including BrCl, Br2, BrOCl, Br2O) can form in chlorinated waters, albe...

Hypobromous acid, a powerful endogenous electrophile: Experimental and theoretical studies.

J. Inorg. Biochem. 146 , 61-8, (2015)

Hypobromous acid (HOBr) is an inorganic acid produced by the oxidation of the bromide anion (Br(-)). The blood plasma level of Br(-) is more than 1,000-fold lower than that of chloride anion (Cl(-)). Consequently, the endogenous production of HOBr is also low...

Pd-catalyzed carbonylative α-arylation of aryl bromides: scope and mechanistic studies.

Chemistry 19(52) , 17926-38, (2013)

Reaction conditions for the three-component synthesis of aryl 1,3-diketones are reported applying the palladium-catalyzed carbonylative α-arylation of ketones with aryl bromides. The optimal conditions were found by using a catalytic system derived from [Pd(d...

Latent carcinogenicity of early-life exposure to dichloroacetic acid in mice.

Carcinogenesis 36 , 782-91, (2015)

Environmental exposures occurring early in life may have an important influence on cancer risk later in life. Here, we investigated carryover effects of dichloroacetic acid (DCA), a small molecule analog of pyruvate with metabolic programming properties, on a...

The Heck reaction in ionic liquids: A multiphasic catalyst system. Carmichael AJ, et al.

Org. Lett. 1(7) , 997-1000, (1999)

Palladium bis (phosphinite)'PCP'-pincer complexes and their application as catalysts in the Suzuki reaction. Bedford RB, et al.

New J. Chem. 24(10) , 745-47, (2000)