(R)-(+)-4-Chloromethyl-2,2-Dimethyl-1,3-Dioxolane
(R)-(+)-4-Chloromethyl-2,2-Dimethyl-1,3-Dioxolane structure
|
Common Name | (R)-(+)-4-Chloromethyl-2,2-Dimethyl-1,3-Dioxolane | ||
|---|---|---|---|---|
| CAS Number | 57044-24-3 | Molecular Weight | 150.603 | |
| Density | 1.1±0.1 g/cm3 | Boiling Point | 156.0±0.0 °C at 760 mmHg | |
| Molecular Formula | C6H11ClO2 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 54.5±18.4 °C | |
| Symbol |
GHS02, GHS05 |
Signal Word | Danger | |
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Enantioselective, palladium-catalyzed alpha-arylation of N-Boc-pyrrolidine.
Tetrahedron Asymmetry 6 , 1283, (1995) This communication discloses the first instance of the enantioselective Pd-catalyzed alpha-arylation of N-Boc-pyrrolidine. The methodology relies on Beak's sparteine-mediated, enantioselective deprotonation of N-Boc-pyrrolidine to form the 2-pyrrolidinolithiu... |
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