1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE structure
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Common Name | 1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE | ||
|---|---|---|---|---|
| CAS Number | 54125-02-9 | Molecular Weight | 172.297 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 181.7±0.0 °C at 760 mmHg | |
| Molecular Formula | C8H16O2Si | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 45.0±0.0 °C | |
| Symbol |
GHS02 |
Signal Word | Warning | |
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Flexible protocol for the chemo- and regioselective building of pyrroles and pyrazoles by reactions of Danishefsky's dienes with 1,2-diaza-1,3-butadienes.
Org. Lett. 10(10) , 1983-6, (2008) The versatility of the Mukaiyama-Michael-type addition/heterocyclization of Danishefsky's diene with 1,2-diaza-1,3-butadienes was applied to the synthesis of both 4 H-1-aminopyrroles and 4,5 H-pyrazoles. Thus, the same reagents furnished different types of hi... |
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Highly selective Diels-Alder reactions of directly connected enyne dienophiles.
J. Am. Chem. Soc. 129 , 645, (2007) The paper describes the course of cycloadditions of Diels-Alder dienophiles containing linked enyne sites, each substituted with activating groups. Consistently, it was found that in the enyne cases the Diels-Alder reaction occurred specifically at the acetyl... |
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Cross-Diels-Alder reactions of 6-oxo-1-sulfonyl-1,6-dihydropyridine-3-carboxylates.
J. Org. Chem. 72 , 2364, (2007) Electron-poor 6-oxo-1-sulfonyl-1,6-dihydropyridine-3-carboxylates 1b-d undergo cross-Diels-Alder reactions with electron-rich dienes 4a-f under hyperbaric conditions, reacting either as dienophiles to yield normal-electron-demand (NED) cycloadducts 10 and/or ... |
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Sulfogriseofulvin derivatives. synthesis by [4 + 2]cycloaddition, structure, properties, crystal structure analysis, and antifungal activity of spiro[1,3-benzoxathiole-2,1'-cyclohex-2'-en]-4'-one 3,3-dioxides.
Arch. Pharm. (Weinheim) 329(7) , 361-70, (1996) Syntheses of substituted, especially of fluoro substituted benzoxathiole 1,1-dioxides, are described. These derivatives were transformed via the Peterson olefination into substituted 2-alkylidene derivatives 27. Diels-Alder reactions of 27 with 1,1-dimethoxy-... |
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Tetrahedron 49 , 1749, (1993)
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J. Org. Chem. 57 , 3605, (1992)
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J. Org. Chem. 57 , 4444, (1992)
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Tetrahedron 49 , 397, (1993)
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Screening of rare earth metal grafted MCM-41 silica for asymmetric catalysis. Gerstberger G and Anwander R.
Microporous Mesoporous Mater. 44 , 303-310, (2001)
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