biphenol

biphenol Structure
biphenol structure
Common Name biphenol
CAS Number 1806-29-7 Molecular Weight 186.207
Density 1.2±0.1 g/cm3 Boiling Point 315.0±0.0 °C at 760 mmHg
Molecular Formula C12H10O2 Melting Point 108-110 °C
MSDS Chinese USA Flash Point 160.8±15.5 °C
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

A theoretical investigation on the Strecker reaction catalyzed by a Ti(IV)-complex catalyst generated from a cinchona alkaloid, achiral substituted 2,2'-biphenol, and tetraisopropyl titanate.

Chemistry 19(5) , 1637-46, (2013)

The mechanism and the origin of selectivity of the asymmetric Strecker reaction catalyzed by a Ti(IV)-complex catalyst generated from a cinchona alkaloid, achiral substituted 2,2'-biphenol, and tetraisopropyl titanate have been investigated by DFT and ONIOM m...

Asymmetric activation of tropos 2,2'-biphenol with cinchonine generates an effective catalyst for the asymmetric strecker reaction of N-tosyl-protected aldimines and ketoimines.

Angew. Chem. Int. Ed. Engl. 46(44) , 8468-70, (2007)

Facile electrochemical determination of tetrabromobisphenol A based on modified glassy carbon electrode.

Talanta 151 , 209-16, (2016)

In this study, surface-functionalized nitrogen-doped graphene was prepared with 1, 3, 6, 8-pyrenetetrasulfonic acid tetrasodium salt in a simple way. The characteristics of the material were demonstrated by UV-vis absorption spectra, X-ray photoelectron spect...

Metabolism of 2,2'- and 3,3'-dihydroxybiphenyl by the biphenyl catabolic pathway of Comamonas testosteroni B-356.

Appl. Environ. Microbiol. 70(1) , 174-81, (2004)

The purpose of this investigation was to examine the capacity of the biphenyl catabolic enzymes of Comamonas testosteroni B-356 to metabolize dihydroxybiphenyls symmetrically substituted on both rings. Data show that 3,3'-dihydroxybiphenyl is by far the prefe...

Degradation of dimeric lignin model compounds by aerobic bacteria isolated from the hindgut of xylophagous termites.

J. Basic Microbiol. 37(3) , 205-11, (1997)

The capability of the intestinal flora from the gut of xylophagous termites of degrading lignin model compounds was investigated. Different dimeric lignin model compounds-degrading bacteria were obtained from the hindgut flora of Mastotermes darwiniensis Frog...

Antioxidant and cyclooxygenase-2-inhibiting activity of 4,4'-biphenol, 2,2'-biphenol and phenol.

Anticancer Res. 29(6) , 2403-10, (2009)

The anthropogenic substance 4,4'-biphenol and its analogues are estrogenic and cytotoxic. It has been previously found that synthesized ortho-dimers of phenolic compounds possess potent antioxidative and anti-inflammatory activity. To clarify the relationship...

High energy radiation-induced crosslinking of histone octamer complexes.

Z. Naturforsch., C, J. Biosci. 39(11-12) , 1075-8, (1984)

Calf thymus histone octamer complexes were irradiated in the native state in N2O-saturated dilute aqueous solution (0.5 g/l, pH 9, [NaClO4] = 1 -4 mol/l) with 50 or 100 ns pulses of 16 MeV electrons or 60Co-gamma-rays. Time resolved light scattering measureme...

Double N-arylation of primary amines: carbazole synthesis from 2,2'-biphenyldiols.

J. Org. Chem. 70(2) , 413-9, (2005)

The double N-arylation of primary amines with 2,2'-biphenylylene ditriflates was investigated for the synthesis of multisubstituted carbazoles. Palladium complexes supported by 2-dicyclohexylphosphino-2'-methylbiphenyl or Xantphos [4,5-bis(diphenylphosphino)-...

Kinetic evaluation of reactivity of bisphenol A derivatives as radical scavengers for methacrylate polymerization.

Biomaterials 21(21) , 2125-30, (2000)

The reactivity of bisphenol A (BPA), diethylstilbestrol (DEST) 2,2'-biphenol (22'BP), 4,4'-biphenol (44'BP) and hydroquinone (HQ) as radical scavengers was examined in 2,2'-azobisisobutyronitrile (AIBN)- and benzoyl peroxide (BPO)-induced methyl methacrylate ...

Broad spectrum antimicrobial biocides target the FabI component of fatty acid synthesis.

J. Biol. Chem. 273(46) , 30316-20, (1998)

The broad spectrum antibacterial properties of 2-hydroxydiphenyl ethers have been appreciated for decades, and their use in consumer products is rapidly increasing. We identify the enoyl-acyl carrier protein reductase (fabI) component of the type II fatty aci...