2,2-DIMETHYLCYCLOHEXANONE

2,2-DIMETHYLCYCLOHEXANONE Structure
2,2-DIMETHYLCYCLOHEXANONE structure
Common Name 2,2-DIMETHYLCYCLOHEXANONE
CAS Number 1193-47-1 Molecular Weight 126.19600
Density 0.892g/cm3 Boiling Point 170.6ºC at 760mmHg
Molecular Formula C8H14O Melting Point -20ºC(lit.)
MSDS Chinese USA Flash Point 50.1ºC
Symbol GHS02
GHS02
Signal Word Warning

Dichloromethane activation. Direct methylenation of ketones and aldehydes with CH2Cl2 promoted by Mg/TiCl4/THF.

Org. Lett. 6(26) , 4961-3, (2004)

[reaction: see text] This Mg-TiCl4-promoted CH2-transfer reaction of CH2Cl2 represents an extremely simple, practical, and efficient methylenation of a variety of ketones and aldehydes, especially in enolizable or sterically hindered ketones such as 2,2-dimet...

Synthesis and antioxidant activity of rosmariquinone and several analogues. Hall CA, et al.

J. Agric. Food Chem. 46(4) , 1303-10, (1998)