Ortho-Hydroxyacetophenone
Ortho-Hydroxyacetophenone structure
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Common Name | Ortho-Hydroxyacetophenone | ||
|---|---|---|---|---|
| CAS Number | 118-93-4 | Molecular Weight | 136.148 | |
| Density | 1.1±0.1 g/cm3 | Boiling Point | 218.4±13.0 °C at 760 mmHg | |
| Molecular Formula | C8H8O2 | Melting Point | 41735ºC | |
| MSDS | Chinese USA | Flash Point | 87.5±12.4 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Carbonyl reductase SCRII from Candida parapsilosis catalyzes anti-Prelog reaction to (S)-1-phenyl-1,2-ethanediol with absolute stereochemical selectivity.
Bioresour. Technol. 102(2) , 483-9, (2011) An (S)-specific carbonyl reductase (SCRII) was purified to homogeneity from Candida parapsilosis by following an anti-Prelog reducing activity of 2-hydroxyacetophenone. Peptide mass fingerprinting analysis shows SCRII belongs to short-chain dehydrogenase/redu... |
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Accessibility and selective stabilization of the principal spin states of iron by pyridyl versus phenolic ketimines: modulation of the 6A1 ↔ 2T2 ground-state transformation of the [FeN4O2]+ chromophore.
Inorg. Chem. 51(15) , 8241-53, (2012) Several potentially tridentate pyridyl and phenolic Schiff bases (apRen and HhapRen, respectively) were derived from the condensation reactions of 2-acetylpyridine (ap) and 2'-hydroxyacetophenone (Hhap), respectively, with N-R-ethylenediamine (RNHCH(2)CH(2)NH... |
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Synthesis, spectral and antimicrobial activity of Zn(II) complexes with Schiff bases derived from 2-hydrazino-5-[substituted phenyl]-1,3,4-thiadiazole and benzaldehyde/2-hydroxyacetophenone/indoline-2,3-dione.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 113 , 393-9, (2013) Zn(II) complexes have been synthesized by reacting zinc acetate with Schiff bases derived from 2-hydrazino-5-[substituted phenyl]-1,3,4-thiadiazole and 2-hydroxyacetophenone/benzaldehyde/indoline-2,3-dione. All these complexes are soluble in DMF and DMSO; low... |
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Synthesis and photoluminescence properties of novel europium complexes of 2'-hydroxyacetophenone and 4,6-diacetylresorcinol.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 69(2) , 664-9, (2008) Novel europium (III) complexes of the formulae Eu(OHAP)(3).2H2O, Eu(OHAP)(3)Phen, Eu2(DAR)(3).4H2O and Eu2(DAR)(3)Phen2 (HOHAP=2'-hydroxyacetophenone, H2DAR=4,6-diacetylresorcinol, Phen=1,10-phenanthroline) have been designed and synthesized in this paper. Th... |
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Palladium-catalyzed carbonylation reaction of aryl bromides with 2-hydroxyacetophenones to form flavones.
Chemistry 18(40) , 12595-8, (2012) Flavone of the month: a general and efficient method for the palladium-catalyzed carbonylative synthesis of flavones has been developed. Starting from aryl bromides and 2-hydroxyacetophenones, the corresponding flavones have been isolated in good yields.Copyr... |
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Organocatalytic Dakin oxidation by nucleophilic flavin catalysts.
Org. Lett. 14(11) , 2806-9, (2012) Flavin catalysts perform the first organocatalytic Dakin oxidation of electron-rich arylaldehydes to phenols under mild, basic conditions. Catechols are readily prepared, and the oxidation of 2-hydroxyacetophenone was achieved. Aerobic oxidation is displayed ... |
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Spectral studies and structure of a 2-hydroxyacetophenone 3-hexamethyleneiminyl thiosemicarbazonate(-2) copper(II) complex containing 1,10-phenanthroline.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 59(6) , 1349-58, (2003) The spectral studies and structure of a ternary complex of copper(II) with 2-hydroxyacetophenone 3-hexamethyliminylthiosemicarbazonate (L(2-)) and 1,10-phenanthroline (phen) are reported. The thiosemicarbazone binds to the metal as a dianionic ONS-donor (L(2-... |
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Dinuclear triple helicates with diazine ligands: X-ray structural, electrochemical, and magnetic studies.
Inorg. Chem. 44(18) , 6299-307, (2005) A series of dinuclear complexes of Mn(III), Fe(III), and Co(III) with two diazine Schiff bases, H2salhn and H2mesalhn, is reported. The Schiff bases are prepared by condensation reactions of hydrazine with salicylaldehyde (H2salhn) and with 2-hydroxyacetophen... |
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Co(II), Cd(II), Hg(II) and U(VI)O₂ complexes of o-hydroxyacetophenone[N-(3-hydroxy-2-naphthoyl)] hydrazone: physicochemical study, thermal studies and antimicrobial activity.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 97 , 683-94, (2012) The o-Hydroxy acetophenone [N-(3-hydroxy-2-naphthoyl)] hydrazone (H(2)o-HAHNH) has been prepared and its structure is confirmed by elemental analysis, IR, (1)H NMR and (13)C NMR spectroscopy. It has been used to produce diverse complexes with Co(II), Cd(II), ... |
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Bivalent transition metal complexes of o-hydroxyacetophenone [N-(3-hydroxy-2-naphthoyl)] hydrazone: spectroscopic, antibacterial, antifungal activity and thermogravimetric studies.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 81(1) , 28-34, (2011) Schiff base complexes of Cu(II), Ni(II) and Zn(II) with the o-hydroxyacetophenone [N-(3-hydroxy-2-naphthoyl)] hydrazone (H(2)o-HAHNH) containing N and O donor sites have been synthesized. Both ligand and its metal complexes were characterized by different phy... |