2,2'-bis(bromomethyl)-1,1'-biphenyl

2,2'-bis(bromomethyl)-1,1'-biphenyl Structure
2,2'-bis(bromomethyl)-1,1'-biphenyl structure
Common Name 2,2'-bis(bromomethyl)-1,1'-biphenyl
CAS Number 38274-14-5 Molecular Weight 340.05300
Density 1.591g/cm3 Boiling Point 421.3ºC at 760mmHg
Molecular Formula C14H12Br2 Melting Point 90-92ºC(lit.)
MSDS Chinese USA Flash Point 244.1ºC
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

Separation and optical resolution of a pair of atrop diastereomers of the octahedral rhodium(III) complex with a nine-membered S,S-chelate ring.

Inorg. Chem. 47(17) , 7450-2, (2008)

Treatment of fac-[Rh(aet) 3] (aet = 2-aminoethanethiolate) with 2,2'-bis(bromomethyl)-1,1'-biphenyl gave a mononuclear rhodium(III) complex with a nine-membered S, S-chelate ring, fac-[Rh(aet)(L)] (2+) ([ 1] (2+), L = 2,2'-bis(2-aminoethylthiomethyl)-1,1'-bip...

Novel α, α-disubstituted a-aminoacids with axial dissymmetry and their N-or C-protected derivatives. Mazaleyrat J-P, et al.

Tetrahedron Asymmetry 8(4) , 619-31, (1997)