Di-tert-butylchlorophosphane
Di-tert-butylchlorophosphane structure
|
Common Name | Di-tert-butylchlorophosphane | ||
|---|---|---|---|---|
| CAS Number | 13716-10-4 | Molecular Weight | 180.655 | |
| Density | 0.951 g/mL at 25 °C(lit.) | Boiling Point | 191.6±0.0 °C at 760 mmHg | |
| Molecular Formula | C8H18ClP | Melting Point | 2-3°C | |
| MSDS | Chinese USA | Flash Point | 61.1±0.0 °C | |
| Symbol |
GHS05 |
Signal Word | Danger | |
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Synthesis and characterization of R2PN=P(iBuNCH2CH2)3N: a new bulky electron-rich phosphine for efficient Pd-assisted Suzuki-Miyaura cross-coupling reactions.
J. Org. Chem. 72 , 2816, (2007) Pro-azaphosphatrane 1a [P(iBuNCH2CH2)3N] reacts with iodine under mild conditions to give [IP(iBuNCH2CH2)3N]I in excellent yield, which on subsequent reaction with ammonia followed by deprotonation with KOtBu provided HN=P(iBuNCH2CH2)3N (3a) in quantitative y... |
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