DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)

DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II) Structure
DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II) structure
Common Name DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)
CAS Number 203714-71-0 Molecular Weight 600.606
Density N/A Boiling Point 383.4ºC at 760 mmHg
Molecular Formula C28H45Cl2OPRu Melting Point 195-197ºC(lit.)
MSDS Chinese USA Flash Point 195.6ºC
Symbol GHS02
GHS02
Signal Word Warning

Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts.

Chem. Rev. 110 , 1746, (2010)

Olefin Metathesis and Beyond A list of abbreviations can be found at the end of this article.

Angew. Chem. Int. Ed. Engl. 39 , 3012, (2000)

The advent of well-defined catalysts for olefin metathesis which combine high activity, durability, and excellent tolerance towards polar functional groups has revolutionized the field. The past decade has seen the rapid embrace of these reagents as tools for...

The development of L2X2Ru=CHR olefin metathesis catalysts: an organometallic success story.

Acc. Chem. Res. 34 , 18, (2001)

In recent years, the olefin metathesis reaction has attracted widespread attention as a versatile carbon-carbon bond-forming method. Many new applications have become possible because of major advances in catalyst design. State-of-the-art ruthenium catalysts ...

Sequential catalysis: a metathesis/dihydroxylation sequence.

Angew. Chem. Int. Ed. Engl. 45 , 1900, (2006)

SYNTHESIS AND SPECTROSCOPIC DIFFERENTIATION OF 2- AND 4-ALKOXYTHIOTETRONIC ACIDS.

Heterocycles 63 , 5-8, (2004)

O-Alkylation of thiotetronic acids gives a mixture of 2- and 4-position enol ether products. Comparison of the physical data revealed that UV spectroscopy was the most reliable method of distinguishing between these related ethers. We have determined that 4-p...

Efficient large-scale synthesis of BILN 2061, a potent HCV protease inhibitor, by a convergent approach based on ring-closing metathesis.

J. Org. Chem. 71 , 7133, (2006)

A multistep scalable synthesis of the clinically important hepatitis C virus (HCV) protease inhibitor BILN 2061 (1) is described. The synthesis is highly convergent and consists of two amide bond formations, one etherification, and one ring-closing metathesis...

Tetrahedron 59 , 6545-6558, (2003)

Schrodi, Y.; Pederson, R. L.

Aldrichimica Acta 40th ed.,, 45, (2007)

Grubbs, R. H.

Tetrahedron 60 , 7117, (2004)

Schuster, M.; Blechert, S.

Angew. Chem. Int. Ed. Engl. 36 , 2036, (1997)