2-Nitroacetophenone
2-Nitroacetophenone structure
|
Common Name | 2-Nitroacetophenone | ||
|---|---|---|---|---|
| CAS Number | 614-21-1 | Molecular Weight | 165.146 | |
| Density | 1.2±0.1 g/cm3 | Boiling Point | 298.6±23.0 °C at 760 mmHg | |
| Molecular Formula | C8H7NO3 | Melting Point | 105-107ºC | |
| MSDS | Chinese USA | Flash Point | 146.9±15.4 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
|
Kinetics of Proton Transfer from Benzoylnitromethane and 1,2-Diphenyl-2-nitroethanone to Various Bases. Resonance, Inductive, Solvation, Steric, and Transition State Hydrogen-Bonding Effects on Intrinsic Rate Constants.
J. Org. Chem. 62(23) , 8162-8170, (1997) The replacement of a hydrogen in nitromethane and in phenylnitromethane by the PhCO group has a strong acidifying effect, i.e., PhCOCH(2)NO(2), 5, is 5.8, 6.6, and 8.6 pK(a) units more acidic than CH(3)NO(2) in water, 50% DMSO-50% water (v/v), and 90% DMSO-10... |
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