(R)-C3-TUNAPHOS
(R)-C3-TUNAPHOS structure
|
Common Name | (R)-C3-TUNAPHOS | ||
|---|---|---|---|---|
| CAS Number | 301847-89-2 | Molecular Weight | 594.61800 | |
| Density | N/A | Boiling Point | 709.9±60.0 ℃(Predicted) | |
| Molecular Formula | C39H32O2P2 | Melting Point | 153-161ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | N/A | |
|
Synthesis of chiral bisphosphines with tunable bite angles and their applications in asymmetric hydrogenation of beta-ketoesters.
J. Org. Chem. 65 , 6223, (2000)
|
|
|
Enantioselective hydrogenation of tetrasubstituted olefins of cyclic beta-(acylamino)acrylates.
J. Am. Chem. Soc. 125 , 9570, (2003) Hydrogenation of a series of cyclic beta-(acylamino)acrylates with tetrasubstituted olefins has been accomplished successfully with the use of Ru catalysts with chiral biaryl ligands such as C3-TunaPhos, and up to over 99% ee's have been achieved. This method... |
|
|
Highly enantioselective asymmetric hydrogenation of alpha-phthalimide ketone: an efficient entry to enantiomerically pure amino alcohols.
J. Am. Chem. Soc. 126 , 1626, (2004) A new type of alpha-phthalimide ketones was hydrogenated in excellent enantioselectivity by using a Ru-(C3-TunePhos) complex as the catalyst. Up to 10 000 turnovers have been achieved in more than 99% ee in the hydrogenation reaction. A dynamic kinetic resolu... |