4-(Dimethylamino)phenylboronic acid

4-(Dimethylamino)phenylboronic acid Structure
4-(Dimethylamino)phenylboronic acid structure
Common Name 4-(Dimethylamino)phenylboronic acid
CAS Number 28611-39-4 Molecular Weight 164.997
Density 1.1±0.1 g/cm3 Boiling Point 329.9±44.0 °C at 760 mmHg
Molecular Formula C8H12BNO2 Melting Point 227 °C(lit.)
MSDS Chinese USA Flash Point 153.3±28.4 °C
Symbol GHS07
GHS07
Signal Word Warning

Synthesis and photophysical investigation of a series of push-pull arylvinyldiazine chromophores.

J. Org. Chem. 8th ed., 77 , 4087-4096, (2012)

A new series of push-pull arylvinyldiazines has been efficiently prepared by aldol condensation between the appropriate methyldiazine and aromatic aldehyde. The optical absorption and emission properties of these chromophores were studied in different solvent...

Nickel-catalyzed Suzuki-Miyaura reaction of aryl fluorides.

J. Am. Chem. Soc. 48th ed., 133 , 19505-19511, (2011)

Two protocols for the nickel-catalyzed cross-coupling of aryl fluorides with aryl boronic esters have been developed. The first employs metal fluoride cocatalysts, such as ZrF(4) and TiF(4), which enable Suzuki-Miyaura reactions of aryl fluorides bearing elec...

Dramatic Effect of the Gelling Cation on the Catalytic Performances of Alginate-Supported Palladium Nanoparticles for the Suzuki-Miyaura Reaction Chtchigrovsky, M.; et al.

Chem. Mater. 8th ed., 24 , 1505-1510, (2012)

Organic dyes incorporating the cyclopentadithiophene moiety for efficient dye-sensitized solar cells Cheng, X.; et al.

Dyes and Pigments 3rd ed., 92 , 1292-1299, (2012)

Rapid access to 4-substituted-pyrones and 2(5H)-furanones via a palladium-catalyzed C-OH bond activation Hu, Y.; et al.

Tetrahedron 38th ed., 67 , 7258-7262, (2011)

Chiral allene-containing phosphines in asymmetric catalysis.

J. Am. Chem. Soc. 45th ed., 133 , 18066-18069, (2011)

We demonstrate that allenes, chiral 1,2-dienes, appended with basic functionality can serve as ligands for transition metals. We describe an allene-containing bisphosphine that, when coordinated to Rh(I), promotes the asymmetric addition of arylboronic acids ...

ortho-Phenylene oligomers with terminal push-pull substitution.

Org. Biomol. Chem. 17th ed., 10 , 3398-3405, (2012)

ortho-Phenylenes are an emerging class of helical oligomers and polymers. We have synthesized a series of push-pull-substituted o-phenylene oligomers (dimethylamino/nitro) up to the octamer. Conformational analysis of the hexamer using a combination of low-te...