4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLAN-2-OL

4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLAN-2-OL Structure
4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLAN-2-OL structure
Common Name 4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLAN-2-OL
CAS Number 16352-18-4 Molecular Weight 164.13900
Density N/A Boiling Point 179.377ºC at 760 mmHg
Molecular Formula C6H13O3P Melting Point 99-106ºC
MSDS Chinese USA Flash Point 79.028ºC
Symbol GHS07
GHS07
Signal Word Warning

Air-stable PinP(O)H as preligand for palladium-catalyzed Kumada couplings of unactivated tosylates.

Org. Lett. 8 , 3457, (2006)

[reaction: see text] Air-stable and easily accessible PinP(O)H enables highly efficient palladium-catalyzed Kumada cross-coupling reactions of aryl tosylates. The in situ generated catalyst proved applicable not only to electron-rich and electron-poor carbocy...