(Trimethylsilyl)methanol
(Trimethylsilyl)methanol structure
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Common Name | (Trimethylsilyl)methanol | ||
|---|---|---|---|---|
| CAS Number | 3219-63-4 | Molecular Weight | 104.223 | |
| Density | 0.8±0.1 g/cm3 | Boiling Point | 119.8±13.0 °C at 760 mmHg | |
| Molecular Formula | C4H12OSi | Melting Point | <0ºC | |
| MSDS | Chinese USA | Flash Point | 31.1±0.0 °C | |
| Symbol |
GHS02, GHS07 |
Signal Word | Warning | |
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Enantioselective esterification of racemic naproxen by lipases in organic solvent.
Enzyme Microb. Technol. 16(4) , 328-33, (1994) Enantioselective esterification of naproxen, 2-(6-methoxy-2-naphthyl) propionic acid, was attempted by lipases in nearly anhydrous isooctane. The nature of the alcohol affects the reactivity and enantioselectivity of the lipase from Candida cylindracea. Alcoh... |
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Efficient kinetic resolution of (R,S)-1-trimethylsilylethanol via lipase-mediated enantioselective acylation in ionic liquids.
Chirality 18(10) , 814-21, (2006) Efficient enantioselective acylation of (R,S)-1-trimethylsilylethanol {(R,S)-1-TMSE} with vinyl acetate catalyzed by immobilized lipase from Candida antarctica B (i.e., Novozym 435) was successfully conducted in ionic liquids (ILs). A remarkable enhancement i... |
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E. Vedejs, G.R. Martinez
J. Am. Chem. Soc. 101 , 6452, (1979)
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K. Baum et al.
J. Org. Chem. 43 , 203, (1978)
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A.R. Katritzky, S. Sengupta
Tetrahedron Lett. 28 , 1847, (1987)
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R.J. Linderman, Y. Suhr
J. Org. Chem. 53 , 1569, (1988)
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Tetrahedron Lett. 28 , 1847, (1987)
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