3-Chloro-2-butanone
3-Chloro-2-butanone structure
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Common Name | 3-Chloro-2-butanone | ||
|---|---|---|---|---|
| CAS Number | 4091-39-8 | Molecular Weight | 106.551 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 114.7±8.0 °C at 760 mmHg | |
| Molecular Formula | C4H7ClO | Melting Point | <-60ºC | |
| MSDS | Chinese USA | Flash Point | 21.1±0.0 °C | |
| Symbol |
GHS02, GHS07 |
Signal Word | Warning | |
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Substrate specificity and enantioselectivity of 4-hydroxyacetophenone monooxygenase.
Appl. Environ. Microbiol. 69(1) , 419-26, (2003) The 4-hydroxyacetophenone monooxygenase (HAPMO) from Pseudomonas fluorescens ACB catalyzes NADPH- and oxygen-dependent Baeyer-Villiger oxidation of 4-hydroxyacetophenone to the corresponding acetate ester. Using the purified enzyme from recombinant Escherichi... |
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Synthesis and activity of ruthenium olefin metathesis catalysts coordinated with thiazol-2-ylidene ligands.
J. Am. Chem. Soc. 130(7) , 2234-45, (2008) A new family of ruthenium-based olefin metathesis catalysts bearing a series of thiazole-2-ylidene ligands has been prepared. These complexes are readily accessible in one step from commercially available (PCy3)2Cl2Ru=CHPh or (PCy3)Cl2Ru=CH(o-iPrO-Ph) and hav... |
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Reaction of α-chloroketones with 1, 4-dianion of acetophenone n-ethoxy-carbonylhydrazone. Matsumura N, et al.
Tetrahedron Lett. 25(40) , 4529-32, (1984)
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Chiral alcohol production by NADH-dependent phenylacetaldehyde reductase coupled with in situ regeneration of NADH.
Eur. J. Biochem. 269(9) , 2394-402, (2002) Phenylacetaldehyde reductase (PAR) produced by styrene-assimilating Corynebacterium strain ST-10 was used to synthesize chiral alcohols. This enzyme with a broad substrate range reduced various prochiral aromatic ketones and beta-ketoesters to yield optically... |
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Reactions of 3-Thiocyano-2-butanone. I. The Preparation of 2-Substituted-4, 5-dimethylthiazoles. Gregory JT and Mathes RA.
J. Am. Chem. Soc. 74(7) , 1719-1720, (1952)
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