Thioacetic acid
Thioacetic acid structure
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Common Name | Thioacetic acid | ||
|---|---|---|---|---|
| CAS Number | 507-09-5 | Molecular Weight | 76.118 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 93.0±0.0 °C at 760 mmHg | |
| Molecular Formula | C2H4OS | Melting Point | -17 °C | |
| MSDS | Chinese USA | Flash Point | 11.1±0.0 °C | |
| Symbol |
GHS02, GHS05, GHS06 |
Signal Word | Danger | |
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Transformation of thiodiglycol by resting cells of Alcaligenes xylosoxydans PGH10.
Biotechnol. Prog. 18(2) , 252-6, (2002) A new strain of Alcaligenes xylosoxydans able to aerobically cometabolize thiodiglycol, the primary hydrolysis product of sulfur mustard, was isolated and tested in a laboratory scale stirred tank reactor. The strain, named PGH10, cannot use TDG as sole carbo... |
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Mechanism-based inhibition of Sir2 deacetylases by thioacetyl-lysine peptide.
Biochemistry 46(50) , 14478-86, (2007) Sir2 protein deacetylases (or sirtuins) catalyze NAD+-dependent conversion of epsilon-amino-acetylated lysine residues to deacetylated lysine, nicotinamide, and 2'-O-acetyl-ADP-ribose. Small-molecule modulation of sirtuin activity might treat age-associated d... |
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Model studies for the thiol-mediated methyl transfer to corrinoids.
Org. Biomol. Chem. 5(13) , 2119-28, (2007) The thiol-dependent methylation of heptamethyl cob(II)yrinate 8r with methyl iodide and methyl tosylate was explored under a variety of conditions. The interaction of the heptamethyl cob(II)yrinate with a variety of thiols was monitored prior to the addition ... |
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Morphological and histochemical characteristics of the lamina propria in scrotal and abdominal testes from postpubertal boars: correlation with the appearance of the seminiferous epithelium.
J. Anat. 199(Pt 4) , 435-48, (2001) This study was undertaken to investigate the morphological characteristics and lectin affinity of the testicular lamina propria in healthy boars and in unilateral and bilateral abdominal cryptorchid boars. The lamina propria of scrotal testes from healthy boa... |
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S-S bond reactivity in metal-perthiocarboxylato compounds.
Dalton Trans. 39(6) , 1511-8, (2010) While M-percarboxylato species are elusive intermediates, their sulfur containing analogues are known in some cases. The feasibility of isolation of M-perthioacetato compounds allowed, in this work, to obtain new insights into the pathways that follow the rea... |
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Synthesis and characterization of toluene-3,4-dithiolatoantimony(III) derivatives with some oxygen and/or sulphur donor ligands.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 74(1) , 67-73, (2009) Replacement reactions of toluene-3,4-dithiolatoantimony(III) chloride with oxygen and/or sulphur donor ligands like benzoic acid, thiobenzoic acid, thioacetic acid, phenol, thiophenol, sodium salicylate and thio glycolic acid in 1:1 molar ratio as well as dis... |
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Non-peptidic cell-penetrating agents: synthesis of oligomeric chiral bicyclic guanidinium vectors.
Org. Biomol. Chem. 10(28) , 5417-30, (2012) Polycationic oligo(chiral bicyclic guanidines) constitute useful non-peptidic penetrating agents for cell uptake and protein surface recognition. We report herein improved and selective procedures for the preparation of oligoguanidinium scaffolds linked throu... |
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Redox and spin-trapping properties of phosphoryldithioacetates.
Phys. Chem. Chem. Phys. 7(2) , 250-7, (2005) The redox properties of ethyl diethoxyphosphoryldithioacetate (1), methyl diethoxyphosphorylfluorodithioacetate (2) and methyl diethoxyphosphoryldifluorodithioacetate (3) were measured by cyclic voltammetry. Addition of free radicals to the three dithioesters... |
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Preparation and properties of trifluorothioacetic acid-S-(trifluoromethyl)ester, CF3C(O)SCF3.
J. Phys. Chem. A 112(27) , 6211-6, (2008) Trifluorothioacetic acid-S-(trifluoromethyl)ester, CF3C(O)SCF3, was prepared by reacting CF3C(O)Cl and AgSCF3 at 50 degrees C. The compound was characterized by (13)C-, (19)F-NMR, UV, and vibrational spectroscopy as well as by gas electron diffraction (GED) a... |
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Cyclic tetrapeptides with thioacetate tails or intramolecular disulfide bridge as potent inhibitors of histone deacetylases.
Bioorg. Med. Chem. Lett. 22(21) , 6770-2, (2012) Two thioacetate tails were introduced to the chlamydocin- and CHAP31-related cyclic tetrapeptides. An intramolecular disulfide bridge could be formed in the CHAP31-related cyclic peptides. Both the thioacetate-tailed and disulfide-bridged peptides were potent... |