4-aminoheptafluorotoluene

4-aminoheptafluorotoluene Structure
4-aminoheptafluorotoluene structure
Common Name 4-aminoheptafluorotoluene
CAS Number 651-83-2 Molecular Weight 233.086
Density 1.6±0.1 g/cm3 Boiling Point 171.7±40.0 °C at 760 mmHg
Molecular Formula C7H2F7N Melting Point N/A
MSDS Chinese USA Flash Point 67.9±18.0 °C
Symbol GHS07
GHS07
Signal Word Warning

Pd(II)-catalyzed carbonylation of C(sp3)-H bonds: a new entry to 1,4-dicarbonyl compounds.

J. Am. Chem. Soc. 49th ed., 132 , 17378-17380, (2010)

Pd(II)-catalyzed β-C(sp(3))-H carbonylation of N-arylamides under CO (1 atm) has been achieved. Following amide-directed C(sp(3))-H cleavage and insertion of CO into the resulting [Pd(II)-C(sp(3))] bond, intramolecular C-N reductive elimination gave the corre...

Pd-catalyzed intermolecular C-H amination with alkylamines.

J. Am. Chem. Soc. 20th ed., 133 , 7652-7655, (2011)

C-H amination of N-aryl benzamides with O-benzoyl hydroxylamines has been achieved with either Pd(II) or Pd(0) catalysts. Furthermore, we demonstrate that secondary amines can be directly used with benzoyl peroxide in a one-pot procedure that proceeds via the...

Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes.

J. Am. Chem. Soc. 49th ed., 133 , 19598-19601, (2011)

Systematic ligand development has led to the identification of novel mono-N-protected amino acid ligands for Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes. A diverse range of organoboron reagents can be used as coupling partners, and the r...

Wasa, M; et. al.

J. Am. Chem. Soc. 132(11) , 3680-3681

Palladium(0)-Catalyzed Alkynylation of C(sp3)-H Bonds He, J.: et. al.

J. Am. Chem. Soc.