3-Iodoaniline

3-Iodoaniline Structure
3-Iodoaniline structure
Common Name 3-Iodoaniline
CAS Number 626-01-7 Molecular Weight 219.023
Density 1.9±0.1 g/cm3 Boiling Point 271.6±0.0 °C at 760 mmHg
Molecular Formula C6H6IN Melting Point 21-24 °C(lit.)
MSDS Chinese USA Flash Point 124.5±22.6 °C
Symbol GHS07
GHS07
Signal Word Warning

Photoinduced intermolecular cross-linking of gas phase triacylglycerol lipid ions.

Eur. J. Mass Spectrom. (Chichester, Eng.) 21 , 287-96, (2015)

Complex mixtures of plant derived triglycerol (TG) lipids are commonly used as feedstock components for the production of industrial polymers. However, there remains a need for the development of analytical strategies to investigate the intrinsic intermolecul...

Copper-catalyzed three-component synthesis of benzothiazolethiones from o-iodoanilines, isocyanide, and potassium sulfide.

Org. Lett. 17(1) , 34-7, (2015)

An efficient copper catalyzed strategy for the synthesis of a variety of benzothiazolethione derivatives has been developed. In the presence of CuCl, the three-component reaction of o-iodoanilines and K2S with p-toluenesulfonylmethyl isocyanide proceeded smoo...

Concise synthesis of (+/-)-horsfiline and (+/-)-coerulescine by tandem cyclisation of iodoaryl alkenyl azides.

Org. Biomol. Chem. 1(1) , 117-22, (2003)

A brief, efficient and economical synthesis of the spiropyrrolidinyloxindoles, horsfiline and coerulescine, has been achieved, starting from itaconic acid and, respectively, p-anisidine or o-iodoaniline. Tandem radical cyclisation of iodoaryl alkenyl azides i...

Application of ynamides in the synthesis of 2-amidoindoles.

Org. Lett. 11(1) , 221-4, (2009)

A Pd-catalyzed, one-pot, two-step synthesis of 2-amidoindoles from ynamides and o-iodoanilines is reported. A key highlight of this sequence is that after the Sonogashira reaction, intramolecular cyclization to the indole occurs spontaneously without activati...

Ionic-liquid-promoted palladium-catalyzed multicomponent cyclocarbonylation of o-iodoanilines and allenes to form methylene-2,3-dihydro-1H-quinolin-4-ones.

J. Org. Chem. 72(9) , 3218-22, (2007)

The palladium-catalyzed cyclocarbonylation reaction of o-iodoanilines with allenes and CO in 1-butyl-3-methylimidazolium hexafluorophosphate afforded 3-methylene-2,3-dihydro-1H-quinolin-4-ones in moderate to excellent yields under a low pressure (5 atm) of CO...

m-[125I]iodoaniline: a useful reagent for radiolabeling biotin.

Int. J. Rad. Appl. Instrum. B 19(3) , 297-301, (1992)

Biotinyl-m-[125I]iodoanilide (BIA) was synthesized by coupling biotin to m-[125I]iodoaniline via a mixed anhydride reaction. m-[125I]Iodoaniline was produced from the tin precursor, which was prepared using a palladium catalyzed reaction of hexabutylditin wit...

Synthesis of novel alpha-C-glycosylamino acids and reverse regioselectivity in Larock's heteroannulation for the synthesis of the indole nucleus.

Biosci. Biotechnol. Biochem. 66(10) , 2273-8, (2002)

An alpha-C-iodoethynylglucose derivative was coupled with an L-serine-derived zinc-copper reagent to give alpha-C-glucosylpropargyl glycine, which underwent palladium catalyzed-heteroannulation with o-iodoaniline to give not alpha-C-glucosyl-tryptophan but al...

Radioiodination of humic substances via azocoupling with 3-[125I] iodoaniline.

Environ. Sci. Technol. 42(11) , 4083-7, (2008)

A new method is described for radiolabeling humic substances (HS) with iodine radioisotopes. The method radiolabels the electron-rich aromatic moieties of HS with the 3-[125I]iodobenzenediazonium ion via azocoupling. The method uses four steps: (i) 3-aminoben...