Benzyl bromide
Benzyl bromide structure
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Common Name | Benzyl bromide | ||
|---|---|---|---|---|
| CAS Number | 100-39-0 | Molecular Weight | 171.035 | |
| Density | 1.4±0.1 g/cm3 | Boiling Point | 198.5±0.0 °C at 760 mmHg | |
| Molecular Formula | C7H7Br | Melting Point | -3 °C | |
| MSDS | Chinese USA | Flash Point | 86.7±0.0 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Structure-activity relationships of a novel pyranopyridine series of Gram-negative bacterial efflux pump inhibitors.
Bioorg. Med. Chem. 23(9) , 2024-34, (2015) Recently we described a novel pyranopyridine inhibitor (MBX2319) of RND-type efflux pumps of the Enterobacteriaceae. MBX2319 (3,3-dimethyl-5-cyano-8-morpholino-6-(phenethylthio)-3,4-dihydro-1H-pyrano[3,4-c]pyridine) is structurally distinct from other known G... |
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Opposite regiospecific ring opening of 2-(cyanomethyl)aziridines by hydrogen bromide and benzyl bromide: experimental study and theoretical rationalization.
J. Org. Chem. 75(13) , 4530-41, (2010) Ring opening of 1-arylmethyl-2-(cyanomethyl)aziridines with HBr afforded 3-(arylmethyl)amino-4-bromobutyronitriles via regiospecific ring opening at the unsubstituted aziridine carbon. Previous experimental and theoretical reports show treatment of the same c... |
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Synthesis and Catalytic Performance of Hierarchically Porous MIL-100(Fe)@polyHIPE Hybrid Membranes.
Macromol. Rapid Commun. 36 , 1605-11, (2015) Metal-organic frameworks (MOFs) nanoparticles in combination with a nonionic surfactant (Pluronic L-121) are used to stabilize dicyclopentadiene (DCPD)-in-water high internal phase emulsions (HIPEs). The resulting HIPEs containing the MIL-100(Fe) nanoparticle... |
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Transient receptor potential ankyrin 1 (TRPA1) channel as emerging target for novel analgesics and anti-inflammatory agents.
J. Med. Chem. 53 , 5085-107, (2010)
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Determination of trace level genotoxic impurities in small molecule drug substances using conventional headspace gas chromatography with contemporary ionic liquid diluents and electron capture detection.
J. Chromatogr. A. 1361 , 217-28, (2014) Ionic liquids (ILs) were used as a new class of diluents for the analysis of two classes of genotoxic impurities (GTIs), namely, alkyl/aryl halides and nitro-aromatics, in small molecule drug substances by headspace gas chromatography (HS-GC) coupled with ele... |
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One-pot thioetherification of aryl halides with thiourea and benzyl bromide in water catalyzed by Cu-grafted furfural imine-functionalized mesoporous SBA-15.
Chem. Commun. (Camb.) 48(64) , 8000-2, (2012) Surface functionalization of SBA-15 followed by its reaction with Cu(OAc)(2) has been carried out to develop a new Cu-grafted functionalized mesoporous material, which catalyzes one-pot three component coupling of different aryl halides with thiourea and benz... |
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Enantioselective nickel-catalyzed cross-coupling reactions of trialkynylindium reagents with racemic secondary benzyl bromides.
Chemistry 14(2) , 741-6, (2008) The first enantioselective sp-sp3 cross-coupling reaction between alkynyl organometals and racemic benzyl bromides is reported. The coupling is performed at room temperature by using NiBr2diglyme and (S)-(iPr)-Pybox as the catalytic system and trialkynylindiu... |
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Electrochemical immobilization of a benzylic film through the reduction of benzyl halide derivatives: deposition onto highly ordered pyrolytic graphite.
Langmuir 27(8) , 5119-25, (2011) The reactivity of electrogenerated benzyl radicals at carbon surfaces was examined through the cathodic reduction of the corresponding bromide derivatives. 4-Nitrobenzyl bromide and benzyl bromide were reduced in N,N-dimethylformamide (DMF) on highly ordered ... |
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Solid-phase synthesis of chiral bicyclic guanidinium oligomers.
J. Comb. Chem. 11(3) , 410-21, (2009) A simple solid-phase synthesis of thioether-linked chiral bicyclic guanidinium oligomers for cell internalization purposes has been developed. The approach is based on a Merrifield-like peptide synthesis on Rinkamide-p-methylbenzhydrylamine resin functionaliz... |
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Organocatalytic activity of cinchona alkaloids: which nitrogen is more nucleophilic?
J. Org. Chem. 74(18) , 7157-64, (2009) The cinchona alkaloids 1a-d react selectively at the quinuclidine ring with benzyl bromide and at the quinoline ring with benzhydrylium ions (diarylcarbenium ions). The kinetics of these reactions have been determined photometrically or conductimetrically and... |