Methyl (2E)-2-butenoate
Methyl (2E)-2-butenoate structure
|
Common Name | Methyl (2E)-2-butenoate | ||
|---|---|---|---|---|
| CAS Number | 623-43-8 | Molecular Weight | 100.116 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 121.0±0.0 °C at 760 mmHg | |
| Molecular Formula | C5H8O2 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 4.4±0.0 °C | |
| Symbol |
GHS02, GHS07 |
Signal Word | Danger | |
|
First total syntheses of the phytotoxins solanapyrones D and E via the domino Michael protocol.
J. Org. Chem. 67(17) , 5969-76, (2002) The phytotoxins solanapyrones D (1) and E (2) have been synthesized from the decalone prepared by the domino Michael reaction of the kinetic enolate of optically pure acetylcyclohexene with methyl crotonate. The decalone was transformed into a solanapyrone co... |
|
|
The vinylogous aldol reaction of unsaturated esters and enolizable aldehydes using the novel Lewis acid aluminum tris(2,6-di-2-naphthylphenoxide).
Org. Lett. 14(11) , 2678-81, (2012) The synthesis of the novel Lewis acid, aluminum tris(2,6-di-2-naphthylphenoxide) (ATNP), and its use in the vinylogous aldol reaction between methyl crotonate and enolizable aldehydes are described. ATNP is related to Yamamoto's Lewis acid, aluminum tris(2,6-... |
|
|
Solvent engineering: an effective tool to direct chemoselectivity in a lipase-catalyzed Michael addition. Priego J, et al.
Tetrahedron 65(2) , 536-539, (2009)
|