(S)-(+)-Epichlorhydrin

(S)-(+)-Epichlorhydrin Structure
(S)-(+)-Epichlorhydrin structure
Common Name (S)-(+)-Epichlorhydrin
CAS Number 67843-74-7 Molecular Weight 92.524
Density 1.2±0.1 g/cm3 Boiling Point 116.1±0.0 °C at 760 mmHg
Molecular Formula C3H5ClO Melting Point −57 °C(lit.)
MSDS Chinese USA Flash Point 33.9±0.0 °C
Symbol GHS02 GHS05 GHS06 GHS08
GHS02, GHS05, GHS06, GHS08
Signal Word Danger

Kinetics of dextran crosslinking by epichlorohydrin: a rheometry and equilibrium swelling study.

Carbohydr. Polym. 92(2) , 1792-8, (2013)

Curing behavior and gel properties of dextran are investigated during its crosslinking by epichlorohydrin (ECH) using rheometry and equilibrium swelling studies. Each ECH/anhydroglucose unit of different molar ratio (0.16-0.99) was added to a known volume of ...

Adsorptive decolorization of methylene blue by crosslinked porous starch.

Carbohydr. Polym. 93(2) , 374-9, (2013)

Crosslinked porous starch (CPS) was prepared by two steps. Native starch was crosslinked with epichlorohydrin and then CPS was prepared by hydrolyzing the crosslinked starch with α-amylase. As a biodegradable and safe adsorbent, CPS was used to remove methyle...

Genotoxic effects of ethylene oxide, propylene oxide and epichlorohydrin in humans: update review (1990-2001).

Mutat. Res. 512(2-3) , 173-94, (2002)

Ethylene oxide (EtO), propylene oxide (PO) and epichlorohydrin (ECH) are important industrial chemicals widely used as intermediates for various synthetic products. EtO and PO are also environmental pollutants. In this review we summarize data published durin...

Development of CMC hydrogels loaded with silver nano-particles for medical applications.

Carbohydr. Polym. 92(1) , 407-13, (2013)

Innovative CMC-based hydrogels with great potentials for usage in medical area were principally synthesized as per two strategies .The first involved reaction of epichlorohydrin in alkaline medium containing silver nitrate to yield silver nano-particles (AgNP...

Behavior of human immunoglobulin G adsorption onto immobilized Cu(II) affinity hollow-fiber membranes.

J. Mol. Recognit. 26(10) , 514-20, (2013)

Iminodiacetic acid (IDA) and tris(2-aminoethyl)amine (TREN) chelating ligands were immobilized on poly(ethylene vinyl alcohol) (PEVA) hollow-fiber membranes after activation with epichlorohydrin or butanediol diglycidyl ether (bisoxirane). The affinity membra...

Determination of epichlorohydrin and 1,3-dichloro-2-propanol in synthesis of cationic etherifying reagent by headspace gas chromatography.

J. Chromatogr. A. 1218(37) , 6518-21, (2011)

This study demonstrates a headspace gas chromatographic(HS-GC) technique for the determination of residual epichlorohydrin (ECH) and generated 1,3-dichloro-2-propanol (DCP) in synthesis process of 3-chloro-2-hydroxypropyltrimethylammonium chloride (CHTAC). By...

Removal of copper ions from water using epichlorohydrin cross-linked beta-cyclodextrin polymer: characterization, isotherms and kinetics.

Water Environ. Res. 86(4) , 296-304, (2014)

Beta-cyclodextrin (beta-CD) cross-linked with epichlorohydrin to form water insoluble beta-cyclodextrin polymer (beta-CDP) has been shown to be an effective sorbent for sorption of organic particles, but the sorption of copper (Cu2+) in aqueous solutions by b...

Physicochemical,in vitrodigestibility and functional properties of carboxymethyl rice starch cross-linked with epichlorohydrin

Food Chem. 141(2) , 1438-44, (2013)

Highlights • Carboxymethyl rice starch was cross-linked with epichlorohydrin. • Significant changes in swelling and water uptake were observed. • Carboxymethylation increased rapidly digestible starch (RDS) content. • ECH cross-linking at appropriate levels r...

Assessment of long-term health risks after accidental exposure using haemoglobin adducts of epichlorohydrin.

Toxicol. Lett. 231(3) , 378-86, (2014)

On September 9th, 2002, two goods trains collided in Bad Münder, Lower Saxony, causing the release of more than 40 metric tonnes of epichlorohydrin (1-chloro-2,3-epoxypropane) into the environment. A human biomonitoring study was performed to evaluate the acc...

Preparation and protein immobilization of magnetic dialdehyde starch nanoparticles.

J. Phys. Chem. B 117(14) , 3720-5, (2013)

Superparamagnetic Fe3O4 nanoparticles were obtained using a hydrolysis product of starch, i.e., α-d-glucose, as the reducing agent and without any additional stabilizer and dispersant by a facile and green method at mild temperature. Magnetic dialdehyde starc...