DimethylBromomalonate

DimethylBromomalonate Structure
DimethylBromomalonate structure
Common Name DimethylBromomalonate
CAS Number 868-26-8 Molecular Weight 211.011
Density 1.6±0.1 g/cm3 Boiling Point 231.3±0.0 °C at 760 mmHg
Molecular Formula C5H7BrO4 Melting Point N/A
MSDS Chinese USA Flash Point 64.7±21.8 °C
Symbol GHS05
GHS05
Signal Word Danger

Highly enantioselective synthesis of nitrocyclopropanes via organocatalytic conjugate addition of bromomalonate to alpha,beta-unsaturated nitroalkenes.

Org. Lett. 11(7) , 1583-6, (2009)

Highly enantioselective synthesis of nitrocyclopropanes was achieved via the organocatalytic conjugate addition of dimethyl bromomalonate to nitroalkenes and the consequent intramolecular cyclopropanation. 6'-Demethyl quinine was found to be the efficient cat...

Manganese (III)-promoted free-radical addition of dimethyl bromomalonate to olefins using an electrochemical regeneration procedure. Nédélec JY and Nohair K.

Synlett 09 , 659-60, (1991)

Stereoselective synthesis of functionalised cyclopropanes from nitroalkenes via an organocatalysed Michael-initiated ring-closure approach. Russo A and Lattanzi A.

Tetrahedron Asymmetry 21(9) , 1155-57, (2010)

Synthesis and 1, 3-dipolar cycloaddition reactions of N-aryl-C, C-dimethoxycarbonylnitrones. Tomioka Y, et al.

J. Heterocycl. Chem. 40(1) , 121-28, (2003)