4-(Trifluoromethyl)benzaldehyde

4-(Trifluoromethyl)benzaldehyde Structure
4-(Trifluoromethyl)benzaldehyde structure
Common Name 4-(Trifluoromethyl)benzaldehyde
CAS Number 455-19-6 Molecular Weight 174.120
Density 1.3±0.1 g/cm3 Boiling Point 176.4±0.0 °C at 760 mmHg
Molecular Formula C8H5F3O Melting Point 1-2°C
MSDS Chinese USA Flash Point 65.6±0.0 °C
Symbol GHS07
GHS07
Signal Word Warning

Ph3As-catalyzed wittig-type olefination of aldehydes with diazoacetate in the presence of Na2S2O4.

J. Org. Chem. 72 , 6628, (2007)

In the presence of sodium hydrosulfite and a catalytic amount of AsPh3 and Fe(TCP)Cl, aldehydes react with ethyl diazoacetate to give the corresponding alpha,beta-unsaturated esters in high yields with excellent stereoselectivities (E/Z > 50/1).

Determination of the equilibrium distibution between alcohol and aldehyde substrates when bound to horse liver alcohol dehydrogenase using magnetic resonance.

Biochemistry 19(24) , 5486-93, (1980)

The interactions of horse liver alcohol dehydrogenase (LADH) with the rho-trifluoromethyl derivatives of benzyl alcohol, benzaldehyde, and benzoic acid have been investigated by use of 19F nuclear magnetic resonance. The aldehyde and alcohol are good substrat...

19F nuclear magnetic resonance observations of aldehyde dismutation catalyzed by horse liver alcohol dehydrogenase.

Arch. Biochem. Biophys. 217(1) , 226-35, (1982)

J. Am. Chem. Soc. 115 , 8570, (1993)

Tetrahedron Lett. 34 , 1925, (1993)

Tetrahedron Asymmetry 5 , 411, (1994)

Tetrahedron 49 , 9613, (1993)

Synthesis and properties of new pyridine-bridged poly (ether-imide) s based on 4-(4-trifluoromethylphenyl)-2, 6-bis [4-(4-aminophenoxy) phenyl] pyridine.

J. Fluor. Chem. 129(1) , 56-63, (2008)