di-t-butylmethylphosphine

di-t-butylmethylphosphine Structure
di-t-butylmethylphosphine structure
Common Name di-t-butylmethylphosphine
CAS Number 6002-40-0 Molecular Weight 160.23700
Density 0.824 g/mL at 25ºC(lit.) Boiling Point 58ºC12 mm Hg(lit.)
Molecular Formula C9H21P Melting Point N/A
MSDS USA Flash Point 60ºC
Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger

Room-temperature Hiyama cross-couplings of arylsilanes with alkyl bromides and iodides.

J. Am. Chem. Soc. 125 , 5616, (2003)

The first method for achieving Hiyama couplings of unactivated alkyl bromides and iodides is reported. The desired carbon-carbon bond formation proceeds under mild conditions (room temperature) with good functional-group tolerance.