[Pd(dppp)(H2O)2](BF4)2
2 Structure](https://image.chemsrc.com/caspic/066/134668-73-8.png)
[Pd(dppp)(H2O)2](BF4)2 structure
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Common Name | [Pd(dppp)(H2O)2](BF4)2 | ||
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| CAS Number | 134668-73-8 | Molecular Weight | 641.71 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C27H30BF4O2P2Pd+ | Melting Point | 175-200°C (decomposition) | |
| MSDS | USA | Flash Point | N/A | |
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Cationic palladium complex catalyzed diastereo- and enantioselective tandem annulation of 2-formylarylboronic acids with allenoates.
Org. Lett. 11 , 4366-4369, (2009) Cationic palladium complex [(dppp)Pd(H(2)O)(2)](2+)(BF(4)(-))(2) catalyzed tandem annulation reactions of 2-formylarylboronic acids and allenoates produce the indenol derivatives diastereo- and enantioselectively in a highly efficient way. |
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Cationic Pd(II)-catalyzed highly enantioselective arylative cyclization of alkyne-tethered enals or enones initiated by carbopalladation of alkynes with arylboronic acids.
Org. Lett. 7th ed., 14 , 1756-1759, (2012) Cationic Pd(II)-catalyzed enantioselective arylative cyclization of alkyne-tethered enals or enones initiated by carbopalladation of alkynes was developed without the necessity of a redox system. |
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Control of chemoselectivity by counteranions of cationic palladium complexes: a convenient enantioselective synthesis of dihydrocoumarins.
Org. Lett. 12 , 108, (2010) High chemoselectivity for the synthesis of two kinds of substituted coumarins controlled by the counteranions of the cationic palladium catalysts is described. The asymmetric version of the reaction for the synthesis of 3-alkylidene dihydrocoumarins is realiz... |
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Cationic palladium-catalyzed [5 + 2] annulation of 2-acylmethoxyarylboronic acids and allenoates: synthesis of 1-benzoxepine derivatives.
J. Org. Chem. 76 , 6350, (2011) The 1-benzoxepine derivatives were synthesized conveniently by cationic palladium-catalyzed [5 + 2] annulation reaction of 2-acylmethoxyarylboronic acids with allenoates in high yields. This annulation involves the intramolecular nucleophilic addition to keto... |
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Cationic Palladium Complex-Catalyzed Diastereoselective Tandem Annulation of 2-Iminoarylboronic Acids with Substituted Alkynes: Enantioselective Synthesis of Aminoindene Derivatives by Double Asymmetric Induction Yu, X.; Lu, X.
Adv. Synth. Catal. 353 , 2805-2813, (2011)
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