Cupric acetylacetonate

Cupric acetylacetonate Structure
Cupric acetylacetonate structure
Common Name Cupric acetylacetonate
CAS Number 13395-16-9 Molecular Weight 261.762
Density N/A Boiling Point 160ºC (9.8 mmHg)
Molecular Formula C10H14CuO4 Melting Point 245ºC
MSDS Chinese USA Flash Point 160°C/10mm
Symbol GHS07
GHS07
Signal Word Warning

Local vanadium release from a calcium sulfate carrier accelerates fracture healing.

J. Orthop. Res. 32(5) , 727-34, (2014)

This study evaluated the efficacy of using calcium sulfate (CaSO4 ) as a carrier for intramedullary delivery of an organic vanadium salt, vanadyl acetylacetonate (VAC) after femoral fracture. VAC can act as an insulin-mimetic and can be used to accelerate fra...

Microbrachytherapy using holmium-166 acetylacetonate microspheres: a pilot study in a spontaneous cancer animal model.

Brachytherapy 12(2) , 171-7, (2013)

Holmium-166 acetylacetonate microspheres ((166)Ho-AcAc-MS) are proposed as an intratumoral radioablation device. This article presents a pilot study in housecats with unresectable liver cancer. Feasibility and tolerability of intratumoral administrations of (...

Evaluation of electrogenerated chemiluminescence from a neutral Ir(III) complex for quantitative analysis in flowing streams.

Analyst 136(10) , 2151-5, (2011)

Though recently Ir(III) complexes have attracted much interest in electrochemiluminescent (ECL) analysis due to their high emission in various wavelengths, there were a few studies reported on its analytical applications. In this study, we evaluate the ECL fr...

An oxygen-chelate complex, palladium bis-acetylacetonate, induces apoptosis in H460 cells via endoplasmic reticulum stress pathway rather than interacting with DNA.

J. Med. Chem. 56(23) , 9601-11, (2013)

Current precious-metal-containing anticancer agents are mostly chelated with N-containing ligands and function by interacting with DNA. In the present study, Pd(acac)2, a Pd(II) complex containing four O-donor ligands, has been evaluated as an active anticanc...

Fully and partially coherent pathways in multiply enhanced odd-order wave-mixing spectroscopy.

J. Phys. Chem. A 114(2) , 817-32, (2010)

Nuclear magnetic resonance spectroscopy relies on using multiple excitation pulses to create multiple quantum coherences that provide great specificity for chemical measurements. Coherent multidimensional spectroscopy (CMDS) is the optical analogue of NMR. Cu...

Spectroscopic studies on Solvatochromism of mixed-chelate copper(II) complexes using MLR technique

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 85(1) , 25-30, (2012)

Mixed-chelate copper(II) complexes with a general formula [Cu(acac)(diamine)]X where acac=acetylacetonate ion, diamine=N,N-dimethyl,N'-benzyl-1,2-diaminoethane and X=BPh(4)(-), PF(6)(-), ClO(4)(-) and BF(4)(-) have been prepared. The complexes were characteri...

Vanadyl bisacetylacetonate protects β cells from palmitate-induced cell death through the unfolded protein response pathway.

J. Biol. Inorg. Chem. 16(5) , 789-98, (2011)

Endoplasmic reticulum (ER) stress induced by free fatty acids (FFA) is important to β-cell loss during the development of type 2 diabetes. To test whether vanadium compounds could influence ER stress and the responses in their mechanism of antidiabetic effect...

VO(acac)(2)/H(2)O(2)/NaI: a mild and efficient combination for the cleavage of dithioacetal derivatives of sugars.

Carbohydr. Res. 346(16) , 2629-32, (2011)

A wide variety of dithioacetal derivatives of sugars can be cleaved easily into the corresponding open-chain aldehydo sugars using an efficient combination of VO(acac)(2)/H(2)O(2)/NaI at 0-5°C. Some of the salient features of this protocol are mild reaction c...

Effect of magnesium acetylacetonate on the signal of organic forms of vanadium in graphite furnace atomic absorption spectrometry.

Talanta 103 , 66-74, (2013)

The aim of this work was to investigate the influence of magnesium acetylacetonate (MgA) on the signal of organic forms of vanadium in xylene solution by graphite furnace atomic absorption spectrometry. MgA alone or mixed with palladium acetylacetonate (PdA) ...

Solvent effect on the optical property of uranyl acetylacetonate monohydrate.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 78(1) , 205-10, (2011)

The lability of the [UO2(acac)2H2O] complex has been exploited to decipher solvent composition of a medium. Successive blue shift of the π-π* band (λmax=282 nm) is observed due to alcohol substitution of increasing chain length in place of water. This observa...