Zinc difluoromethanesulfinate 95

Zinc difluoromethanesulfinate 95 Structure
Zinc difluoromethanesulfinate 95 structure
Common Name Zinc difluoromethanesulfinate 95
CAS Number 1355729-38-2 Molecular Weight 295.5484928
Density N/A Boiling Point N/A
Molecular Formula C2H2F4O4S2Zn Melting Point N/A
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

Practical and innate carbon-hydrogen functionalization of heterocycles.

Nature 492 , 95-100, (2012)

Nitrogen-rich heterocyclic compounds have had a profound effect on human health because these chemical motifs are found in a large number of drugs used to combat a broad range of diseases and pathophysiological conditions. Advances in transition-metal-mediate...

A new reagent for direct difluoromethylation.

J. Am. Chem. Soc. 134 , 1494-1497, (2012)

Molecular scaffolds containing alkylfluorine substituents are desired in many areas of chemical research from materials to pharmaceuticals. Herein, we report the invention of a new reagent (Zn(SO(2)CF(2)H)(2), DFMS) for the innate difluoromethylation of organ...

Radical-based regioselective C-H functionalization of electron-deficient heteroarenes: scope, tunability, and predictability.

J. Am. Chem. Soc. 135 , 12122-12134, (2013)

Radical addition processes can be ideally suited for the direct functionalization of heteroaromatic bases, yet these processes are only sparsely used due to the perception of poor or unreliable control of regiochemistry. A systematic investigation of factors ...

Sulfinate derivatives: dual and versatile partners in organic synthesis.

Org. Biomol. Chem. 12(48) , 9743-59, (2014)

Sulfinic acids and their salts have recently emerged as versatile coupling partners to efficiently access a wide variety of hetero- and carbocyclic compounds, under relatively mild conditions. Their growing importance is attributable to their dual capacity fo...