Thioxomanganese

Thioxomanganese Structure
Thioxomanganese structure
Common Name Thioxomanganese
CAS Number 18820-29-6 Molecular Weight 87.003
Density 3,99 g/cm3 Boiling Point N/A
Molecular Formula MnS Melting Point 1610ºC
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

Unusual formation of single-crystal manganese sulfide microboxes co-mediated by the cubic crystal structure and shape.

Angew. Chem. Int. Ed. Engl. 51(29) , 7267-70, (2012)

Kept cubic: MnS microboxes, which act as an anode material for lithium ion batteries, are synthesized by a simple H(2)S gas sulfidation approach (TEM images show porous and hollow microcubes and a microbox). The formation of the single crystals is aided by th...

Rapid and effective labeling of brain tissue using TAT-conjugated CdS:Mn/ZnS quantum dots.

Chem. Commun. (Camb.) (25) , 3144-6, (2005)

TAT (a cell penetrating peptide)-conjugated CdSratioMn/ZnS quantum dots (Qdots), intra-arterially delivered to a rat brain, rapidly (within a few minutes) labeled the brain tissue without manipulating the blood-brain-barrier (BBB). Qdot loading was sufficient...

Carcinogenic sulfide salts of nickel and cadmium induce H2O2 formation by human polymorphonuclear leukocytes.

Cancer Res. 50(23) , 7564-70, (1990)

Some derivatives of nickel, cadmium, and cobalt are carcinogenic in humans and/or animals but their mechanisms of action are not known. We show that they are capable of stimulating human polymorphonuclear leukocytes (PMNs), as measured by H2O2 formation, a kn...

Use of a paramagnetic substance, colloidal manganese sulfide, as an NMR contrast material in rats.

J. Nucl. Med. 25(5) , 604-7, (1984)

Paramagnetic pharmaceuticals ( magnetopharmaceuticals ) that are suitably distributed into specific organ systems or diseased sites might be clinically useful for tissue contrast enhancement in nuclear magnetic resonance images. To determine whether an insolu...

The big red shift of photoluminescence of Mn dopants in strained CdS: a case study of Mn-doped MnS-CdS heteronanostructures.

J. Am. Chem. Soc. 132(19) , 6618-9, (2010)

The red photoluminescence of Mn dopants in MnS-CdS heteronanostructures has been observed for the first time. The red photoluminescence at 650 nm derives from emission due to the (4)T(1) --> (6)A(1) transition of Mn(2+) dopants in a CdS matrix exposed to giga...

Mineral-assisted pathways in prebiotic synthesis: photoelectrochemical reduction of carbon(+IV) by manganese sulfide.

J. Am. Chem. Soc. 126(36) , 11247-53, (2004)

Photoelectrochemistry on mineral surfaces has the potential to play a central role in the prebiotic syntheses of building blocks for biomolecules. In this study, photoreduction of C(+IV) as bicarbonate is used as a probe to investigate the photoelectrochemica...

Hydrothermal synthesis of a doped Mn-Cd-S solid solution as a visible-light-driven photocatalyst for H2 evolution.

ChemSusChem 4(2) , 269-73, (2011)

The effect of metal doping (i.e., with Cr, Fe, Ni, Cu, Zn, Ag and Sn) on the crystal structure of hydrothermally synthesized Mn(1-x)Cd(x) S (where x≈0.1) is studied with the aim of enhancing photocatalytic activity. In contrast to the low-crystalline, undoped...

Manganese sulfide formation via concomitant microbial manganese oxide and thiosulfate reduction.

Environ. Microbiol. 13(12) , 3275-88, (2011)

The dissimilatory metal-reducing bacterium, Shewanella oneidensis MR-1 produced γ-MnS (rambergite) nanoparticles during the concurrent reduction of MnO₂ and thiosulfate coupled to H₂ oxidation. To investigate effect of direct microbial reduction of MnO₂ on Mn...

A facile route for the synthesis of poly(N-vinylcarbazole)/manganese sulphide quantum dots nanocomposites with enhanced optical properties.

J. Nanosci. Nanotechnol. 8(11) , 6031-7, (2008)

This communication describes a facile route for the synthesis of manganese sulphide (MnS) quantum dots (QDs) contained in poly(N-vinyl carbazole) (PNVC) nanocomposites. MnS QDs were synthesized using the single-source precursor method by thermolysing tetramet...

Hydrothermal Synthesis of Pure r-Phase Manganese(II) Sulfide without the Use of Organic Reagents Michel FM, et al.

Chem. Mater. 18 , 1726-1736, (2006)