4,4'-Di-tert-butyl-2,2'-bipyridine
4,4'-Di-tert-butyl-2,2'-bipyridine structure
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Common Name | 4,4'-Di-tert-butyl-2,2'-bipyridine | ||
|---|---|---|---|---|
| CAS Number | 72914-19-3 | Molecular Weight | 268.397 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 395.4±42.0 °C at 760 mmHg | |
| Molecular Formula | C18H24N2 | Melting Point | 159-161ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | 150.2±19.5 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Phenanthrene synthesis by iron-catalyzed [4+2] benzannulation between alkyne and biaryl or 2-alkenylphenyl Grignard reagent.
J. Am. Chem. Soc. 133(17) , 6557-9, (2011) The [4+2] benzannulation reaction of internal or terminal alkynes with 2-biaryl, 2-heteroarylphenyl, or 2-alkenylphenyl Grignard reagents in the presence of Fe(acac)(3), 4,4'-di-tert-butyl-2,2'-bipyridyl, and 1,2-dichloro-2-methylpropane takes place at room t... |
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Iridium(III) silyl alkyl and iridacyclic compounds supported by 4,4'-di-tert-butyl-2,2'-bipyridyl.
Chemistry 12(36) , 9323-35, (2006) Treatment of IrCl(3)x H(2)O with one equivalent of 4,4'-di-tert-butyl-2,2'-bipyridyl (dtbpy) in N,N-dimethylformamide (dmf) afforded [IrCl(3)(dmf)(dtbpy)] (1). Alkylation of 1 with Me(3)SiCH(2)MgCl resulted in C--Si cleavage of the Me(3)SiCH(2) group and form... |
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