(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl structure
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Common Name | (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl | ||
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| CAS Number | 76189-55-4 | Molecular Weight | 622.67 | |
| Density | N/A | Boiling Point | 724.3±55.0 °C at 760 mmHg | |
| Molecular Formula | C44H32P2 | Melting Point | 283-286 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 419.0±37.8 °C | |
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The preparation of bi-functional organophosphine oxides as potential antitumor agents.
Eur. J. Med. Chem. 45 , 5527-30, (2010) Following our previously reported pyridinyl phosphine oxides as antitumor agents, we targeted the commercially available C(2)-axial chiral organophosphine ligand catalysts, such as 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP) 1 and 2,2',6,6'-tetrametho... |
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Desymmetrization of meso-dienyne by asymmetric Pauson-Khand type reaction catalysts.
Chem. Commun. (Camb.) , 1134-1135, (2004) Desymmetrization of the meso dienynes, such as propargyl 1-vinylallyl N-tosylamides (1a-c) and propargyl 1-vinylallyl ethers (1d-e), by asymmetric Pauson-Khand type reaction catalysts was studied. The corresponding vinyl substituted bicyclic pentenones (2 and... |
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Catalytic enantioselective hetero-Diels-Alder reactions of an azo compound.
J. Am. Chem. Soc. 128 , 16482, (2006) This communication describes studies in which an azo hetero-Diels-Alder adduct was furnished in high regio- and enantioselectivity using azopyridine as a reagent and silver as a catalyst. The obtained hetero-Diels-Alder adduct was easily converted to the corr... |
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