Chemical Communications 2004-05-07

Desymmetrization of meso-dienyne by asymmetric Pauson-Khand type reaction catalysts.

Nakcheol Jeong, Dong Hoon Kim, Jun Hun Choi

Index: Chem. Commun. (Camb.) , 1134-1135, (2004)

Full Text: HTML

Abstract

Desymmetrization of the meso dienynes, such as propargyl 1-vinylallyl N-tosylamides (1a-c) and propargyl 1-vinylallyl ethers (1d-e), by asymmetric Pauson-Khand type reaction catalysts was studied. The corresponding vinyl substituted bicyclic pentenones (2 and 3) were obtained with high diastereoselectivity and enantioselectivity.

Structure	Name/CAS No.	Molecular Formula	Articles
	(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl CAS:76189-55-4	C₄₄H₃₂P₂

The preparation of bi-functional organophosphine oxides as p...
2010-11-01
[Eur. J. Med. Chem. 45 , 5527-30, (2010)]

Catalytic enantioselective hetero-Diels-Alder reactions of a...
2006-12-27
[J. Am. Chem. Soc. 128 , 16482, (2006)]

[Tetrahedron 50 , 335, (1994)]

[Organic Synth. 71 , 1, (1993)]

Ohkuma, T. et al.
[J. Am. Chem. Soc. 117 , 2675, (1995)]

Desymmetrization of meso-dienyne by asymmetric Pauson-Khand type reaction catalysts.

Abstract

Related Compounds