Chemical Communications 2004-05-07

Desymmetrization of meso-dienyne by asymmetric Pauson-Khand type reaction catalysts.

Nakcheol Jeong, Dong Hoon Kim, Jun Hun Choi

文献索引：Chem. Commun. (Camb.) , 1134-1135, (2004)

摘要

Desymmetrization of the meso dienynes, such as propargyl 1-vinylallyl N-tosylamides (1a-c) and propargyl 1-vinylallyl ethers (1d-e), by asymmetric Pauson-Khand type reaction catalysts was studied. The corresponding vinyl substituted bicyclic pentenones (2 and 3) were obtained with high diastereoselectivity and enantioselectivity.

结构式	名称/CAS号	分子式	全部文献
	R-(+)-1,1'-联萘-2,2'-双二苯膦 CAS:76189-55-4	C₄₄H₃₂P₂

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Desymmetrization of meso-dienyne by asymmetric Pauson-Khand type reaction catalysts.

摘要

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