1,3-bis((S)-2,2-dimethyl-1-(o-tolyl)propyl)-4,5-dihydro-1H-imidazol-3-ium iodide

1,3-bis((S)-2,2-dimethyl-1-(o-tolyl)propyl)-4,5-dihydro-1H-imidazol-3-ium iodide Structure
1,3-bis((S)-2,2-dimethyl-1-(o-tolyl)propyl)-4,5-dihydro-1H-imidazol-3-ium iodide structure
Common Name 1,3-bis((S)-2,2-dimethyl-1-(o-tolyl)propyl)-4,5-dihydro-1H-imidazol-3-ium iodide
CAS Number 1237025-59-0 Molecular Weight 518.51600
Density N/A Boiling Point N/A
Molecular Formula C27H39IN2 Melting Point N/A
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

New chiral N-heterocyclic carbene ligands in palladium-catalyzed alpha-arylations of amides: conformational locking through allylic strain as a device for stereocontrol.

Chemistry 16 , 6300, (2010)

New Enders/Herrmann-type chiral N-heterocyclic carbene (NHC) ligands have been developed and applied in asymmetric palladium-catalyzed intramolecular alpha-arylations of amides. The best ligands feature the bulky tert-butyl group and ortho-substituted aryl gr...