(R)-(-)-Solketal
(R)-(-)-Solketal structure
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Common Name | (R)-(-)-Solketal | ||
|---|---|---|---|---|
| CAS Number | 14347-78-5 | Molecular Weight | 132.158 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 188.5±0.0 °C at 760 mmHg | |
| Molecular Formula | C6H12O3 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 80.0±0.0 °C | |
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In vitro toxicities of experimental jet fuel system ice-inhibiting agents.
Sci. Total Environ. 274(1-3) , 209-18, (2001) One research emphasis within the Department of Defense has been to seek the replacement of operational compounds with alternatives that pose less potential risk to human and ecological systems. Alternatives to glycol ethers, such as diethylene glycol monometh... |
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Effects of glycerol acetonide on adrenergic neurotransmission in isolated rabbit heart.
Arzneimittelforschung 42(11) , 1288-91, (1992) In the present investigation, the solvent glycerol acetonide (GA, CAS 100-79-8) was added (110 mg/min) to the Tyrode buffer perfusing an isolated rabbit heart preloaded with 14C-noradrenaline (NA). GA inhibits the neuronal uptake of NA but stimulates its spon... |
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Fourier transform near-infrared vibrational circular dichroism used for on-line monitoring the epimerization of 2,2-dimethyl-1,3-dioxolane-4-methanol: A pseudo racemization reaction.
Chirality 18(10) , 775-82, (2006) Near-infrared (near-IR) Fourier transform vibrational circular dichroism (FT-VCD) spectroscopy has been used to monitor the epimerization of (S)-(+)-2,2-dimethyl-1,3-dioxolane-4-methanol (S-DDM). The near-IR-VCD spectra display clear isolated VCD bands at the... |
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Synthesis of sn-glycero-1-phosphocholine.
J. Lipid Res. 22 , 879, (1981) The preparation of sn-glycero-1-phosphocholine is described. 2,3-O-Isopropylidene-sn-glycerol is condensed first with the 1,2-dimethylethenylene phosphorochloridate in the presence of triethylamine to yield the cyclic phosphotriester derivative. Choline p-tol... |
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[Change in behavior of mice and rats under the effect of dimethyl-2,2 hydroxymethyl-4 dioxolanne-1,3 (glycerol acetonide)].
Ann. Pharm. Fr. 44(6) , 487-94, (1986)
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[Interference of the action of dimethyl-2,2-hydroxymethyl-4 dioxolane- 1,3 (AG) with various active pharmacomolecules on the central nervous system].
Ann. Pharm. Fr. 45(6) , 445-51, (1987)
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Synthesis and application of highly reactive amino linkers for functional oligonucleotides.
Curr. Protoc. Nucleic Acid Chem. Chapter 4 , Unit 4.48.1-23, (2012) Oligonucleotides are functionalized by conjugation with a variety of molecules, and aliphatic amino linkers have been frequently used as a tether for their modifications. This unit describes the syntheses and applications of novel amino linkers having a carba... |
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Transglucosylation with 6'-chloro-6'-deoxysucrose and immobilized isomaltulose-producing microorganisms using 2,2-dimethyl-1,3-dioxolane-4-methanol and its related compounds as acceptors. Steric and chemical requirement of the glucosyl acceptor.
Carbohydr. Res. 264(2) , 237-51, (1994) Enantioselective and diastereoselective alpha-D-glucosylation of 2,3-O-isopropylidene-erythritol was observed in transglucosylation with a synthetic donor using three kinds of immobilized isomaltulose-producing microorganisms. Several related compounds, inclu... |
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Extension of fourier transform vibrational circular dichroism into the near-infrared region: continuous spectral coverage from 800 to 10 000 cm(-1).
Appl. Spectrosc. 58(9) , 1057-64, (2004) We report the first vibrational circular dichroism (VCD) spectra with continuous coverage from 800 cm(-1) in the mid-infrared (MIR) region to 10 000 cm(-1) in the near-infrared (NIR) region. This coverage is illustrated with MIR and NIR absorbance and VCD spe... |
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Deuterium isotope effect on enantioselectivity in the Comamonas testosteroni quinohemoprotein alcohol dehydrogenase-catalyzed kinetic resolution of rac-2,2-dimethyl-4-hydroxymethyl-1,3-dioxolane, solketal.
Biochim. Biophys. Acta 1647(1-2) , 297-302, (2003) Isotopic substitution provides an effective tool to probe the mechanism of enzyme-catalyzed reactions. To our knowledge, kinetic isotope effects on the enantioselectivity of enzymes have not been reported. We investigated the effect of deuterium substitution ... |