2,2-dimethylpropyl carbonochloridate
2,2-dimethylpropyl carbonochloridate structure
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Common Name | 2,2-dimethylpropyl carbonochloridate | ||
|---|---|---|---|---|
| CAS Number | 20412-38-8 | Molecular Weight | 150.60300 | |
| Density | 1.003 g/mL at 25ºC(lit.) | Boiling Point | 55ºC36 mm Hg(lit.) | |
| Molecular Formula | C6H11ClO2 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 32ºC | |
| Symbol |
GHS02, GHS05, GHS06 |
Signal Word | Danger | |
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Correlation of the rates of solvolysis of neopentyl chloroformate-a recommended protecting agent.
Int. J. Mol. Sci. 12(2) , 1161-74, (2011) The specific rates of solvolysis of neopentyl chloroformate (1) have been determined in 21 pure and binary solvents at 45.0 °C. In most solvents the values are essentially identical to those for ethyl and n-propyl chloroformates. However, in aqueous-1,1,1,3,3... |
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Alkylation of alkenes: ethylaluminum sesquichloride-mediated hydro-alkyl additions with alkyl chloroformates and di-tert-butylpyrocarbonate.
J. Am. Chem. Soc. 126(33) , 10319-30, (2004) A general method for the hydro-alkyl addition to the nonactivated C=C double bond of alkenes using alkyl chloroformates (primary, secondary), 12, and di-tert-butylpyrocarbonate, 52, mediated by ethylaluminum sesquichloride (Et(3)Al(2)Cl(3)) has been developed... |
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