thallium (i) ethoxide
thallium (i) ethoxide structure
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Common Name | thallium (i) ethoxide | ||
|---|---|---|---|---|
| CAS Number | 20398-06-5 | Molecular Weight | 249.44400 | |
| Density | 3.522 g/mL at 25 °C(lit.) | Boiling Point | 130°C | |
| Molecular Formula | C2H5OTl | Melting Point | -3°C | |
| MSDS | Chinese USA | Flash Point | >230 °F | |
| Symbol |
GHS06, GHS08, GHS09 |
Signal Word | Danger | |
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The first scorpionate ligand based on diazaphosphole.
Dalton Trans. 44 , 20242-53, (2015) The reaction of PhBCl2 with 1H-1,2,4-λ(3)-diazaphosphole in the presence of NEt3 gives a new scorpionate ligand, phenyl-tris(1,2,4-diazaphospholyl)borate (PhTdap). The coordination behaviour of this ligand toward transition and non-transition metals has been ... |
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En route to surface-bound electric field-driven molecular motors.
J. Org. Chem. 68 , 5091, (2003) Four caltrop-shaped molecules that might be useful as surface-bound electric field-driven molecular motors have been synthesized. The caltrops are comprised of a pair of electron donor-acceptor arms and a tripod base. The molecular arms are based on a carbazo... |
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Use of thallium(I) ethoxide in Suzuki cross coupling reactions.
Org. Lett. 2(17) , 2691-4, (2000) [reaction: see text]Thallium(I) ethoxide promotes Suzuki cross couplings for a range of vinyl- and arylboronic acids with vinyl and aryl halide partners in good to excellent yields. This reagent offers distinct advantages over thallium(I) hydroxide in terms o... |
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Thallium(I) sandwich, multidecker, and ether complexes stabilized by weakly-coordinating anions: a spectroscopic, structural, and theoretical investigation.
J. Am. Chem. Soc. 129(4) , 881-94, (2007) The reaction of thallium ethoxide with [H(OEt2)2][H2N{B(C6F5)3}2] in diethyl ether afforded [Tl(OEt2)3][H2N{B(C6F5)3}2] (2a), [Tl(OEt2)4][H2N{B(C6F5)3}2] (2b), or [Tl(OEt2)2][H2N{B(C6F5)3}2].CH2Cl2 (2c), depending on the reaction conditions. The dication in t... |
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Effectiveness of sodium sugar sulfates on acute toxicity of paraquat in mice.
J. Pharmacobiodyn. 12(8) , 456-60, (1989) The reduction of acute toxicity of paraquat dichloride (PQ) in mice was studied by several sodium sugar sulfates such as dextran sulfate (DS), cellulose sulfate (CS), chondroitin sulfate (CDS), sucrose sulfate (SS) and glucose sulfate (GS). When sugar sulfate... |
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Coupling of biologically active steroids to conjugating arms through ether linkages for use in immunochemistry.
Steroids 67(1) , 71-5, (2002) Conjugation of haptens through ether linkages avoids leakage problems in immunoassays, but this procedure is not easily applied to most steroids that bear low reacting hydroxyls. A new technique allowing the ether coupling of biologically active steroids with... |
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Chan, T. H.; Li, C. J.; Wei, Z. Y.,
J. Chem. Soc. Chem. Commun. , 505, (1990)
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Andrews, P. C.; Peatt, A. C.; Raston, C. L.
Tetrahedron Lett. 43 , 7541, (2002)
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