Bis(2-methoxyethyl)aminosulphur trifluoride
Bis(2-methoxyethyl)aminosulphur trifluoride structure
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Common Name | Bis(2-methoxyethyl)aminosulphur trifluoride | ||
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| CAS Number | 202289-38-1 | Molecular Weight | 221.241 | |
| Density | 1.2±0.1 g/cm3 | Boiling Point | 256.3±25.0 °C at 760 mmHg | |
| Molecular Formula | C6H14F3NO2S | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 108.8±23.2 °C | |
| Symbol |
GHS02, GHS05, GHS06 |
Signal Word | Danger | |
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[Bis(2-methoxyethyl)amino]sulfur trifluoride, the Deoxo-Fluor reagent: application toward one-flask transformations of carboxylic acids to amides.
J. Org. Chem. 69 , 2573, (2004) The use of the Deoxo-Fluor reagent is a versatile method for acyl fluoride generation and subsequent one-flask amide coupling. It provides mild conditions and facile purification of the desired products in good to excellent yields. We have explored the utilit... |
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Fluorination of thiocarbonyl compounds with Bis(2-methoxyethyl)aminosulfur trifluoride (Deoxo-fluor reagent): A facile synthesis of gem-difluorides
J. Org. Chem. 65 , 4830, (2000) A variety of thiocarbonyl derivatives (thioketone, thioester, thioamide, dithioester, and dithiocarbamate) were converted to the corresponding gem-difluorides in excellent yields on reaction with the fluorinating agent, bis(2-methoxyethyl)aminosulfur trifluor... |
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One-pot route to new alpha,alpha-difluoroamides and alpha-ketoamides.
J. Org. Chem. 68 , 6063, (2003) New alpha,alpha-difluoroamides (4a-d, 6a-d) and alpha-ketoamides (5a-d, 7a-d) result from one-pot reactions of alpha-ketoacids, RCOCO(2)H (R = C(6)H(5), CH(3), CH(3)CH(2), thienyl) (1a-d) with bis(2-methoxyethyl)aminosulfur trifluoride [(CH(3)OCH(2)CH(2))(2)N... |
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Synthesis , 2561, (2002)
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Fluorinating agent with high thermal stability. S. Lal-Gauri et al.
J. Org. Chem. 64 , 7048, (1999)
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R.P. Singh, J.M. Shreeve
J. Fluor. Chem. 116 , 23, (2002)
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