4,7-dibromo-5-fluorobenzo[c][1,2,5]thiadiazole

4,7-dibromo-5-fluorobenzo[c][1,2,5]thiadiazole Structure
4,7-dibromo-5-fluorobenzo[c][1,2,5]thiadiazole structure
Common Name 4,7-dibromo-5-fluorobenzo[c][1,2,5]thiadiazole
CAS Number 1347736-74-6 Molecular Weight 311.957
Density 2.3±0.1 g/cm3 Boiling Point 321.3±37.0 °C at 760 mmHg
Molecular Formula C6HBr2FN2S Melting Point 162 °C
MSDS Chinese USA Flash Point 148.1±26.5 °C
Symbol GHS07
GHS07
Signal Word Warning

Increased open circuit voltage in fluorinated benzothiadiazole-based alternating conjugated polymers.

Chem. Commun. (Camb.) 47 , 11026-11028, (2011)

Small band-gap conjugated polymers based on monofluoro- and difluoro-substituted benzothiadiazole were developed. Highly efficient polymer solar cells (PCE as high as 5.40%) could be achieved for devices made from these polymers.

Fluorinated copolymer PCPDTBT with enhanced open-circuit voltage and reduced recombination for highly efficient polymer solar cells.

J. Am. Chem. Soc. 134(36) , 14932-14944, (2012)

A novel fluorinated copolymer (F-PCPDTBT) is introduced and shown to exhibit significantly higher power conversion efficiency in bulk heterojunction solar cells with PC(70)BM compared to the well-known low-band-gap polymer PCPDTBT. Fluorination lowers the pol...