![]() N-p-Tosylazetidine structure
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Common Name | N-p-Tosylazetidine | ||
---|---|---|---|---|
CAS Number | 7730-45-2 | Molecular Weight | 211.281 | |
Density | 1.3±0.1 g/cm3 | Boiling Point | 337.6±35.0 °C at 760 mmHg | |
Molecular Formula | C10H13NO2S | Melting Point | 119-122ºC(lit.) | |
MSDS | USA | Flash Point | 158.0±25.9 °C |
Ag(I)-catalyzed regioselective ring-opening of N-tosylaziridine and N-tosylazetidine with S-, O-, and N-nucleophiles and tethered dinucleophiles.
J. Org. Chem. 76(5) , 1475-8, (2011) [Ag(COD)(2)]PF(6) catalyzes the ring-opening of N-tosylaziridines and -azetidines with alcohols, amines, thiols, and related tethered 1,2-ethane dinucleophiles. Initial rate studies and DFT-based evaluation of stepwise energetics suggest an inverse relationsh... |
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