n,n-dimethylformamide dineopentyl acetal
n,n-dimethylformamide dineopentyl acetal structure
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Common Name | n,n-dimethylformamide dineopentyl acetal | ||
|---|---|---|---|---|
| CAS Number | 4909-78-8 | Molecular Weight | 231.37500 | |
| Density | 0.829 g/mL at 25 °C(lit.) | Boiling Point | 85-87 °C10 mm Hg(lit.) | |
| Molecular Formula | C13H29NO2 | Melting Point | 253.5℃ | |
| MSDS | Chinese USA | Flash Point | 125 °F | |
| Symbol |
GHS02, GHS07 |
Signal Word | Warning | |
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Improved approach for anchoring N alpha-9-fluorenylmethyloxycarbonylamino acids as p-alkoxybenzyl esters in solid-phase peptide synthesis.
Int. J. Pept. Protein Res. 26 , 92, (1985) Several Fmoc-amino acids have been esterified by use of N,N-dimethylformamide dineopentyl acetal to 2,4,5-trichlorophenyl 3'-(4''-hydroxymethyl-phenoxy)propionate, and the resultant handle derivatives were purified and then quantitatively coupled onto aminome... |
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Preparation of l-serine and l-cystine stereospecifically labeled with deuterium at the ß-position. Oba M, et al.
Tetrahedron Asymmetry 17(12) , 1890-1894, (2006)
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On-column gas chromatographic synthesis of 1,3-dialkyl (c = 1-10), benzyl, and cyclohexyl barbiturate derivatives.
Clin. Toxicol. 16(2) , 189-99, (1980) Procedures are described for the on-column gas chromatographic synthesis of various N-alkyl-N-alkyl barbiturates where groups added to the nitrogens are benzyl, cyclohexyl, or straight chains with 1 to 10 carbons. The 1,3-dialkyl barbiturates having methyl, e... |
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Application of N,N-dimethylformamide dineopentyl acetal for efficient anchoring of N alpha-9-fluorenylmethyloxycarbonylamino acids as p-alkoxybenzyl esters in solid-phase peptide synthesis.
Int. J. Pept. Protein Res. 23(4) , 342-9, (1984) The attachment of Fmoc-amino acids onto p- alkoxybenzyl alcohol resins via DCC-DMAP coupling suffers from two different problems: formation of dimers and racemization. The use of N,N-dimethylformamide dineopentyl acetal for the preparation of Fmoc- aminoacylo... |