1,4,8,11-Tetraazacyclotetradecane
1,4,8,11-Tetraazacyclotetradecane structure
|
Common Name | 1,4,8,11-Tetraazacyclotetradecane | ||
|---|---|---|---|---|
| CAS Number | 295-37-4 | Molecular Weight | 200.324 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 321.1±10.0 °C at 760 mmHg | |
| Molecular Formula | C10H24N4 | Melting Point | 184-186 °C(lit.) | |
| MSDS | USA | Flash Point | 153.0±14.1 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
|
Role of ligand to control the mechanism of nitric oxide reduction of copper(II) complexes and ligand nitrosation.
Inorg. Chem. 50(23) , 11868-76, (2011) The nitric oxide reactivity of two copper(II) complexes, 1 and 2 with ligands L(1) and L(2), respectively, [L(1) = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, L(2) = 5,5,7-trimethyl-[1,4]-diazepane] have been studied. The copper(II) center in... |
|
|
Zn(II)-cyclam based chromogenic sensors for recognition of ATP in aqueous solution under physiological conditions and their application as viable staining agents for microorganism.
Inorg. Chem. 50(9) , 4162-70, (2011) Two chromogenic complexes, L.Zn (where L is (E)-4-((4-(1,4,8,11-tetraazacyclotetradecan-1-ylsulfonyl)phenyl)diazenyl)-N,N-dimethylaniline) and its [2]pseudorotaxane form (α-CD.L.Zn), were found to bind preferentially to adenosine triphosphate (ATP), among all... |
|
|
A reversible nanoswitch as an ON-OFF photocatalyst.
Chem. Commun. (Camb.) 48(96) , 11730-2, (2012) The two states of a new nanomechanical switch were quantitatively and reversibly populated in several subsequent switching cycles using either Cu(+) or cyclam as chemical inputs. State II was demonstrated to cis-trans isomerise diazastilbene upon irradiation ... |
|
|
Liposome encapsulation of a photochemical NO precursor for controlled nitric oxide release and simultaneous fluorescence imaging.
Mol. Pharm. 9(10) , 2950-5, (2012) Described are photochemical studies of the nitric oxide precursors, trans-Cr(L)(ONO)(2)(+) (L = cyclam = 1,4,8,11-tetraazacyclotetradecane, CrONO, or L = mac = 5,7-dimethyl-6-anthracenylcyclam, mac-CrONO) encapsulated in phosphatidylcholine liposomes. The lip... |
|
|
Photochemistry of trans-Cr(cyclam)(ONO)2+, a nitric oxide precursor.
Inorg. Chem. 50(10) , 4453-62, (2011) Experimental and density functional theory (DFT) studies are described that are focused on outlining the reactivity of the known photochemical nitric oxide precursor trans-Cr(cyclam)(ONO)(2)(+) ("CrONO", cyclam = 1,4,8,11-tetrazacycltetradecane). Studies in b... |
|
|
Model studies of methyl CoM reductase: methane formation via CH3-S bond cleavage of Ni(I) tetraazacyclic complexes having intramolecular methyl sulfide pendants.
Inorg. Chem. 51(9) , 5173-87, (2012) The Ni(I) tetraazacycles [Ni(dmmtc)](+) and [Ni(mtc)](+), which have methylthioethyl pendants, were synthesized as models of the reduced state of the active site of methyl coenzyme M reductase (MCR), and their structures and redox properties were elucidated (... |
|
|
Reactivity, photolability, and computational studies of the ruthenium nitrosyl complex with a substituted cyclam fac-[Ru(NO)Cl2(κ3N4,N8,N11(1-carboxypropyl)cyclam)]Cl·H2O.
Dalton Trans. 40(24) , 6420-32, (2011) Chemical reactivity, photolability, and computational studies of the ruthenium nitrosyl complex with a substituted cyclam, fac-[Ru(NO)Cl(2)(κ(3)N(4),N(8),N(11)(1-carboxypropyl)cyclam)]Cl·H(2)O ((1-carboxypropyl)cyclam = 3-(1,4,8,11-tetraazacyclotetradecan-1-y... |
|
|
The photochemistry of [Fe(III)N3(cyclam-ac)]PF6 at 266 nm.
Chemistry 18(10) , 3043-55, (2012) The photochemistry of iron azido complexes is quite challenging and poorly understood. For example, the photochemical decomposition of [Fe(III)N(3)(cyclam-ac)]PF(6) ([1]PF(6)), where cyclam-ac represents the 1,4,8,11-tetraazacyclotetradecane-1-acetate ligand,... |
|
|
Characterization of a macrocyclic end-on peroxido copper complex.
Angew. Chem. Int. Ed. Engl. 52(3) , 870-3, (2013)
|
|
|
A novel tetrabranched neurotensin(8-13) cyclam derivative: synthesis, 64Cu-labeling and biological evaluation.
J. Inorg. Biochem. 105(6) , 821-32, (2011) New macrocyclic 1,4,8,11-tetraazacyclotetradecane (cyclam) derivatives with 1, 2 and 4 neurotensin(8-13) units 4, 5 and 7 have been synthesized. Compounds 4 and 5 were prepared by the reaction of non-stabilized neurotensin(8-13) and cyclamtetrapropionic acid ... |