Tetrabutylammonium perchlorate
Tetrabutylammonium perchlorate structure
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Common Name | Tetrabutylammonium perchlorate | ||
|---|---|---|---|---|
| CAS Number | 1923-70-2 | Molecular Weight | 341.914 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C16H36ClNO4 | Melting Point | 211-215 °C | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS03, GHS07 |
Signal Word | Danger | |
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High-turnover hypoiodite catalysis for asymmetric synthesis of tocopherols.
Science 345(6194) , 291-4, (2014) The diverse biological activities of tocopherols and their analogs have inspired considerable interest in the development of routes for their efficient asymmetric synthesis. Here, we report that chiral ammonium hypoiodite salts catalyze highly chemo- and enan... |
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Tandem cyclization of α-cyano α-alkynyl aryl ketones induced by tert-butyl hydroperoxide and tetrabutylammonium iodide.
Org. Lett. 14(23) , 6024-7, (2012) The radical cascade protocol of the α-cyano α-TMS/aryl-capped alkynyl aryl ketones promoted by tert-butyl hydroperoxide under catalysis with tetrabutylammonium iodide in refluxing benzene has been developed, leading to the construction of a variety of highly ... |
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Synthesis, crystal structure and anaerobic DNA photocleavage of ruthenium complexes [Ru(tpy)(dpoq)Cl](+) and [Ru(tpy)(dpoq)CH3CN](2.).
J. Inorg. Biochem. 149 , 80-7, (2015) Two new Ru(II) complexes [Ru(tpy)(dpoq)Cl](+)1 and [Ru(tpy)(dpoq)CH3CN](2+)2 (tpy = 2,2':6',2''-terpyridine; dpoq = dipyrido[1,2,5]oxadiazolo[3,4-b]quinoxaline) have been synthesized and characterized by elemental analysis, (1)H NMR, electrospray ionization m... |
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A simple method for patterning poly(dimethylsiloxane) barriers in paper using contact-printing with low-cost rubber stamps.
Anal. Chim. Acta 858 , 82-90, (2015) This paper presents a simple and low-cost method for patterning poly(dimethylsiloxane) (PDMS) barriers in porous support such as paper for the construction of flexible microfluidic paper-based analytical devices (μPADs). The fabrication method consisted of co... |
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Alloyed copper chalcogenide nanoplatelets via partial cation exchange reactions.
ACS Nano 8(8) , 8407-18, (2014) We report the synthesis of alloyed quaternary and quinary nanocrystals based on copper chalcogenides, namely, copper zinc selenide-sulfide (CZSeS), copper tin selenide-sulfide (CTSeS), and copper zinc tin selenide-sulfide (CZTSeS) nanoplatelets (NPLs) (∼20 nm... |
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Construction of hybrid films of silver nanoparticles and polypyridine ruthenium complexes on substrates.
Dalton Trans. 44 , 15244-9, (2015) Hybrid films of functional molecules and metal nanoparticles have been considered to be novel photo-functional devices. Here we have successfully constructed hybrid films of silver nanoparticles and ruthenium polypyridine derivatives on substrates. In order t... |
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Photon upconversion and photocurrent generation via self-assembly at organic-inorganic interfaces.
J. Phys. Chem. Lett. 6 , 4510-7, (2015) Molecular photon upconversion via triplet-triplet annihilation (TTA-UC), combining two or more low energy photons to generate a higher energy excited state, is an intriguing strategy to surpass the maximum efficiency for a single junction solar cell (<34%). H... |
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RNA editing in eag potassium channels: biophysical consequences of editing a conserved S6 residue.
Channels (Austin.) 6(6) , 443-52, (2012) RNA editing at four sites in eag, a Drosophila voltage-gated potassium channel, results in the substitution of amino acids into the final protein product that are not encoded by the genome. These sites and the editing alterations introduced are K467R (Site 1,... |
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Quantitative imaging of ion transport through single nanopores by high-resolution scanning electrochemical microscopy.
J. Am. Chem. Soc. 134(24) , 9856-9, (2012) Here we report on the unprecedentedly high resolution imaging of ion transport through single nanopores by scanning electrochemical microscopy (SECM). The quantitative SECM image of single nanopores allows for the determination of their structural properties,... |
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Photoinduced ligand exchange and DNA binding of cis-[Ru(phpy)(phen)(CH3CN)2]+ with long wavelength visible light.
J. Inorg. Biochem. 121 , 77-87, (2013) The complex cis-[Ru(phpy)(phen)(CH3CN)2](+) (phpy=2-phenylpyridine, phen=1,10-phenanthroline) was investigated as a potential photodynamic therapy (PDT) agent. This complex presents desirable photochemical characteristics including a low energy absorption tai... |