1-Methoxyacetone
1-Methoxyacetone structure
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Common Name | 1-Methoxyacetone | ||
|---|---|---|---|---|
| CAS Number | 5878-19-3 | Molecular Weight | 88.105 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 118.9±13.0 °C at 760 mmHg | |
| Molecular Formula | C4H8O2 | Melting Point | 78ºC | |
| MSDS | USA | Flash Point | 25.0±0.0 °C | |
| Symbol |
GHS02 |
Signal Word | Warning | |
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Protonation thermochemistry of selected hydroxy- and methoxycarbonyl molecules.
J. Phys. Chem. A 109(51) , 11851-9, (2005) The gas-phase basicities of a representative set of hydroxy- and methoxycarbonyl compounds (hydroxyacetone, 1, 3-hydroxybutanone, 2, 3-hydroxy-3-methylbutanone, 3, 1-hydroxy-2-butanone, 4, 4-hydroxy-2-butanone, 5, 5-hydroxy-2-pentanone, 6, methoxyacetone, 7, ... |
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Mechanism of the double aldol reaction: the first spectroscopic characterization of a carbon-bound boron enolate derived from carboxylic esters.
J. Am. Chem. Soc. 124(36) , 10759-64, (2002) The novel doubly borylated enolate is identified as an intermediate of the double aldol reaction of acetate esters. As a precursor to the formation of the doubly borylated enolate, carbon-bound boron enolates of carboxylic esters are spectroscopically charact... |
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