Phosphine
Phosphine structure
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Common Name | Phosphine | ||
|---|---|---|---|---|
| CAS Number | 7803-51-2 | Molecular Weight | 33.998 | |
| Density | 1.15 (vs air) | Boiling Point | -87.2±9.0 °C at 760 mmHg | |
| Molecular Formula | H3P | Melting Point | -133.78ºC | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS02, GHS05, GHS06, GHS09 |
Signal Word | Danger | |
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Suppressor of Deltex mediates Pez degradation and modulates Drosophila midgut homeostasis.
Nat. Commun. 6 , 6607, (2015) Pez functions as an upstream negative regulator of Yorkie (Yki) to regulate intestinal stem cell (ISC) proliferation and is essential for the activity of the Hippo pathway specifically in the Drosophila midgut epithelium. Here we report that Suppressor of Del... |
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Molybdenum complex with bulky chelates as a functional model for molybdenum oxidases.
Inorg. Chem. 53(23) , 12416-27, (2014) The novel bulky Schiff base chelate ligand [(4,5-diisopropyl-1H-pyrrole-2-yl)methylene]-4-(tert-butyl)aniline ((iPr2)HL) bearing two isopropyl groups close to the pyrrole nitrogen atom reacts with MoCl2(dme)O2 (dme = 1,2-dimethoxyethane) to give the stericall... |
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Experimental and theoretical mechanistic investigation of the iridium-catalyzed dehydrogenative decarbonylation of primary alcohols.
J. Am. Chem. Soc. 137(2) , 834-42, (2015) The mechanism for the iridium-BINAP catalyzed dehydrogenative decarbonylation of primary alcohols with the liberation of molecular hydrogen and carbon monoxide was studied experimentally and computationally. The reaction takes place by tandem catalysis throug... |
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Surface functionalisation of carbon for low cost fabrication of highly stable electrochemical DNA sensors.
Biosens. Bioelectron. 71 , 25-9, (2015) An alternative strategy for surface tethering of DNA probes, where highly reactive glassy carbon (GC) substrates are prepared via electrochemical hydrogenation and electrochemical/chemical chlorination is reported. Thiolated DNA probes and alkanethiols were s... |
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LDL-R promoting activity of peptides derived from human PCSK9 catalytic domain (153-421): design, synthesis and biochemical evaluation.
Eur. J. Med. Chem. 92 , 890-907, (2015) High level of Low Density Lipoprotein-Cholesterol (LDL-C) in circulation in the blood is associated with an elevated risk of cardiovascular disease (CVD) and stroke. Currently the statin drugs which inhibit the enzyme HMG-CoA reductase responsible for cholest... |
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An amplified electrochemical strategy using DNA-QDs dendrimer superstructure for the detection of thymine DNA glycosylase activity.
Biosens. Bioelectron. 71 , 249-55, (2015) A triple-signal amplification strategy was proposed for highly sensitive and selective detection of thymine DNA glycosylase (TDG) by coupling a dendrimer-like DNA label with the electrochemical method and quantum dots (QDs) tagging. The DNA-QDs dendrimer-like... |
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Large-scale identification of core-fucosylated glycopeptide sites in pancreatic cancer serum using mass spectrometry.
J. Proteome Res. 14(4) , 1968-78, (2015) Glycosylation has significant effects on protein function and cell metastasis, which are important in cancer progression. It is of great interest to identify site-specific glycosylation in search of potential cancer biomarkers. However, the abundance of glyco... |
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Glycoform analysis of recombinant and human immunodeficiency virus envelope protein gp120 via higher energy collisional dissociation and spectral-aligning strategy.
Anal. Chem. 86(14) , 6959-67, (2014) Envelope protein gp120 of human immunodeficiency virus (HIV) is armored with a dense glycan shield, which plays critical roles in envelope folding, immune-evasion, infectivity, and immunogenicity. Site-specific glycosylation profiling of recombinant gp120 is ... |
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15-Oxoeicosatetraenoic acid is a 15-hydroxyprostaglandin dehydrogenase-derived electrophilic mediator of inflammatory signaling pathways.
Chem. Biol. Interact. 234 , 144-53, (2015) Bioactive lipids govern cellular homeostasis and pathogenic inflammatory processes. Current dogma holds that bioactive lipids, such as prostaglandins and lipoxins, are inactivated by 15-hydroxyprostaglandin dehydrogenase (15PGDH). In contrast, the present res... |
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Phosphine fumigation and residues in dry-cured ham in commercial applications.
Meat Science 107 , 57-63, (2015) Dry-cured hams often become infested with ham mites (Tyrophagus putrescentiae) during the aging process. Methyl bromide has been used to fumigate dry cured ham plants and is the only available fumigant that is effective at controlling ham mite infestations. H... |