1,3-DIMESITYL-1H-IMIDAZOL-3-IUM-2-IDE

1,3-DIMESITYL-1H-IMIDAZOL-3-IUM-2-IDE Structure
1,3-DIMESITYL-1H-IMIDAZOL-3-IUM-2-IDE structure
Common Name 1,3-DIMESITYL-1H-IMIDAZOL-3-IUM-2-IDE
CAS Number 141556-42-5 Molecular Weight 304.42900
Density N/A Boiling Point 442.706ºC at 760 mmHg
Molecular Formula C21H24N2 Melting Point 140ºC
MSDS Chinese USA Flash Point 199.09ºC
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning

Normal-to-Abnormal NHC Rearrangement of Al(III) , Ga(III) , and In(III) Trialkyl Complexes: Scope, Mechanism, Reactivity Studies, and H2 Activation.

Chemistry 21 , 17959-72, (2015)

The present contribution reports experimental and theoretical mechanistic investigations on a normal-to-abnormal (C2-to-C4-bonded) NHC rearrangement processes occurring with bulky group 13 metal NHC adducts, including the scope of such a reactivity for Al com...