2,4,6-TRI-TERT-BUTYLANILINE

2,4,6-TRI-TERT-BUTYLANILINE Structure
2,4,6-TRI-TERT-BUTYLANILINE structure
Common Name 2,4,6-TRI-TERT-BUTYLANILINE
CAS Number 961-38-6 Molecular Weight 261.44500
Density 0.896g/cm3 Boiling Point 302ºC at 760 mmHg
Molecular Formula C18H31N Melting Point 145-147 °C(lit.)
MSDS Chinese USA Flash Point 123.7ºC
Symbol GHS07
GHS07
Signal Word Warning

Chemistry of Diazaphospholephosphines. 2. Exocyclic Phosphine-Sulfido, -Selenido, and -Imido Derivatives of a Diazaphospholephosphine System. Crystal and Molecular Structures of Two Diazaphospholephosphine Imines: 4-(Difluoro((p-cyanotetrafluorophenyl)imino)phosphorano)-2,5-dimethyl-2H-1,2,3sigma(2)-diazaphosphole and 4-(Bis(dimethylamino)(((pentamethylcyclopentadienyl)dichlorotitanio)imino)phosphorano)-2,5-dimethyl-2H-1,2,3sigma(2)-diazaphosphole.

Inorg. Chem. 38(12) , 2791-2801, (1999)

The substituted-exo-phosphine (X = F, NMe(2), OCH(2)CF(3)) diazaphospholephosphines are exclusively oxidized at this center with either chalcogens (S, Se) or azides to phosphoranodiazaphospholes. Oxidation imparts a dramatic upfield shift of the phosphorus NM...