Tetrakis(triphenylphosphine)palladium

Tetrakis(triphenylphosphine)palladium Structure
Tetrakis(triphenylphosphine)palladium structure
Common Name Tetrakis(triphenylphosphine)palladium
CAS Number 14221-01-3 Molecular Weight 1155.56
Density N/A Boiling Point 360ºC at 760 mmHg
Molecular Formula C72H60P4Pd Melting Point 103-107 °C
MSDS Chinese USA Flash Point 181.7ºC
Symbol GHS08
GHS08
Signal Word Warning

Controlled self-assembly of a pyrene-based bolaamphiphile by acetate ions: from nanodisks to nanofibers by fluorescence enhancement.

Soft Matter 11 , 4424-9, (2015)

In this paper, a pyrene moiety is incorporated into a bolaamphiphile to form a novel molecule denoted PRB. Above the critical micelle concentration, PRB forms nanodisks in the aqueous solution. The addition of acetate ions induces a morphological change in se...

Enzymatic primer-extension with glycerol-nucleoside triphosphates on DNA templates.

PLoS ONE 4(3) , e4949, (2009)

Glycerol nucleic acid (GNA) has an acyclic phosphoglycerol backbone repeat-unit, but forms stable duplexes based on Watson-Crick base-pairing. Because of its structural simplicity, GNA is of particular interest with respect to the possibility of evolving func...

Zwitterionic red fluorescent polymeric nanoparticles for cell imaging.

Macromol. Biosci. 14(10) , 1361-7, (2014)

Phospholipid monomer and aggregation-induced emission (AIE) dye-based dimers are incorporated via reversible addition-fragmentation transfer polymerization to afford cross-linked zwitterionic fluorescent copolymers. Such copolymers are prone to self-assembly ...

Planar-rotor architecture based pyrene-vinyl-tetraphenylethylene conjugated systems: photophysical properties and aggregation behavior.

Org. Biomol. Chem. 13 , 10663-74, (2015)

Four pyrene-vinyl-tetraphenylethylene based conjugated materials were synthesized and characterized by FT-IR, NMR, and mass spectroscopy. The photophysical (including absorption, fluorescence, and fluorescence lifetime) and aggregation properties in tetrahydr...

Palladium-catalyzed formylation of organic halides with carbon monoxide and tin hydride.

J. Am. Chem. Soc. 108 , 452, (1986)

The ketene-surrogate coupling: catalytic conversion of aryl iodides into aryl ketenes through ynol ethers.

Angew. Chem. Int. Ed. Engl. 53(34) , 8980-4, (2014)

tert-Butoxyacetylene is shown to undergo Sonogashira coupling with aryl iodides to yield aryl-substituted tert-butyl ynol ethers. These intermediates participate in a [1,5]-hydride shift, which results in the extrusion of isobutylene and the generation of ary...

Platinum(II)-Based Metallo-Supramolecular Polymer with Controlled Unidirectional Dipoles for Tunable Rectification.

ACS Appl. Mater. Interfaces 7 , 19034-42, (2015)

A platinum(II)-based, luminescent, metallo-supramolecular polymer (PolyPtL1) having an inherent dipole moment was synthesized via complexation of Pt(II) ions with an asymmetric ligand L1, containing terpyridyl and pyridyl moieties. The synthesized ligand and ...

I. Pri-Bar, O. Buchanan

J. Org. Chem. 51 , 734, (1986)

S. Murahashi et al.

Tetrahedron Lett. 29 , 2973, (1988)

Kotora, M; Xu, C.; Negishi, E.

J. Org. Chem. 62 , 8957, (1997)