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| 中文名 | 碱式碳酸镍(II)水合物 |
|---|---|
| 英文名 | Nickel(II) carbonate hydroxide hydrate |
| 中文别名 | 碱式碳酸镍水合物 |
| 英文别名 |
MFCD00150875
Nickel(II) Carbonate Basic Tetrahydrate |
| 分子式 | C2H10NiO10 |
|---|---|
| 分子量 | 252.78800 |
| 精确质量 | 251.96300 |
| PSA | 157.64000 |
| 储存条件 | 室温 |
| 计算化学 | 1、 疏水参数计算参考值（XlogP）：未确定 2、 氢键供体数量：5 3、 氢键受体数量：8 4、 可旋转化学键数量：0 5、 拓扑分子极性表面积（TPSA）：68.2 6、 重原子数量：10 7、 表面电荷：-1 8、 复杂度：18.8 9、 同位素原子数量：0 10、 确定原子立构中心数量：0 11、 不确定原子立构中心数量：0 12、 确定化学键立构中心数量：0 13、 不确定化学键立构中心数量：0 14、 共价键单元数量：7 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 22 40 43 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful if swallowed. Limited evidence of a carcinogenic effect. May cause sensitization by skin contact. Potential Health Effects Eye: Causes eye irritation. No information regarding eye irritation and other potential effects was found. Skin: May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause severe irritation and possible burns. May cause dermatitis. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Causes respiratory tract irritation. May cause allergic respiratory reaction. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: Material will not burn. Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Limits CAS# 39430-27-8: United States OSHA: 1 mg/m3 TWA (as Ni) (listed under Nickel sol compounds). Belgium - TWA: (listed as nickel soluble compounds): 0.1 mg/m3 VL (as Ni) Malaysia: (listed as nickel soluble compounds): 0.1 mg/m3 TWA (inhalable fraction, as Ni) Netherlands: (listed as nickel soluble compounds): 0.1 mg/m3 MAC Ni) Spain: (listed as nickel soluble compounds): 0.1 mg/m3 VLA-ED (as Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron. Respirators: A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: green Odor: odorless pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: soluble in ammonia and in diluted acids Specific Gravity/Density: Molecular Formula: CH4Ni3O7.xH2O Molecular Weight: 304.11 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: None reported. Incompatibilities with Other Materials: None reported. Hazardous Decomposition Products: Irritating and toxic gases. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 39430-27-8: QR6260000 LD50/LC50: CAS# 39430-27-8: Oral, rat: LD50 = 840 mg/kg. Carcinogenicity: Nickel (II) hydroxide carbonate hydrate, pure, (ca 45-47% Ni) - California: carcinogen, initial date 5/7/04 (listed as Nickel compound NTP: Known carcinogen (listed as Nickel compounds). IARC: Group 1 carcinogen (listed as Nickel compounds). Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 22 Harmful if swallowed. R 40 Limited evidence of a carcinogenic effect. R 43 May cause sensitization by skin contact. Safety Phrases: S 22 Do not breathe dust. S 36/37 Wear suitable protective clothing and gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 39430-27-8: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 39430-27-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 39430-27-8 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 1、急性毒性：大鼠经口LD50：840 mg/kg；
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
MUTATION DATA
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| 危害码 (欧洲) | T |
|---|---|
| 风险声明 (欧洲) | R45;R20/21/22;R36/37/38;R42/43 |
| 安全声明 (欧洲) | S26-S45-S53-S36-S37-S39 |