查看所有供应商和价格请点击：
| 中文名 | 氨基磺酸镍 |
|---|---|
| 英文名 | Nickel(II) Sulfamate w/w aq. Soln., Reagent Grade |
| 中文别名 | 胺基磺酸鎳 |
| 英文别名 |
Nickel bis(sulphamidate)
nickel(2+),disulfamate EINECS 237-396-1 MFCD00137261 |
| 密度 | 1.913g/cm3 |
|---|---|
| 熔点 | 205ºC |
| 分子式 | H4N2NiO6S2 |
| 分子量 | 250.86500 |
| 精确质量 | 249.88600 |
| PSA | 155.54000 |
| LogP | 0.90380 |
| 外观性状 | 绿色至带蓝色的晶体 |
| 储存条件 | 1.贮存于通风、干燥的库房中。包装必须完整密封，注意防潮。 2.运输过程中要防雨淋和日光暴晒。 |
| 稳定性 | 1.常温常压下稳定 避免的物料，碱 水溶液与碱金属 碱土金属和许多有机无机的活性化学药品是不相溶的。易潮解。易溶于水。在高温时失去结晶水同时分解。2.失火时，可用水、砂土和灭火器扑救。 3.在干燥空气中缓慢风化、 受热时会失去4个水生成无水物， 温度高于110℃时开始分解并形成碱式盐， 继续加热生成棕黑色的三氧化二镍和绿色的氧化亚镍混合物。 |
| 分子结构 | 1、摩尔折射率：无可用的 2、摩尔体积（cm3/mol）：无可用的 3、等张比容（90.2K）：无可用的 4、表面张力（dyne/cm）：无可用的 5、介电常数：无可用的 6、极化率（10-24cm3）：无可用的 7、单一同位素质量：249.886425 Da 8、标称质量：250 Da 9、平均质量：250.865 Da |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:2 3.氢键受体数量:8 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积183 7.重原子数量:11 8.表面电荷:0 9.复杂度:79.2 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:3 |
| 更多 | 1. 性状：绿色结晶。 2. 密度（g/mL,25/4℃）：1.55 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：易溶于水，溶于液氨、 乙醇， 微溶于丙酮， 水溶液呈酸性。 |
|
Section 1. Chemical Product and Company Identification Nickel Sulfamate, Solution Common Name/ Trade Name Manufacturer Commercial Name(s) Synonym
Chemical Name Chemical Family Nickel Sulfamate, Solution Section 4. First Aid Measures Eye ContactCheck for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately. Skin ContactIn case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. Serious Skin ContactWash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention. InhalationIf inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Serious InhalationNot available. IngestionDo NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Serious IngestionNot available. Section 5. Fire and Explosion Data Flammability of the Product Non-flammable. Auto-Ignition Temperature Not applicable. Flash PointsNot applicable. Flammable LimitsNot applicable. Products of CombustionNot available. Fire Hazards in Presence of Not applicable. Various Substances Explosion Hazards in Presence Non-explosive in presence of open flames and sparks, of shocks. of Various Substances Fire Fighting MediaNot applicable. and Instructions Special Remarks onNot available. Fire Hazards Special Remarks on Explosion Not available. Hazards Section 6. Accidental Release Measures Small SpillDilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Large SpillAbsorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Nickel Sulfamate, Solution Section 7. Handling and Storage PrecautionsDo not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents. StorageKeep container tightly closed. Keep container in a cool, well-ventilated area. Section 8. Exposure Controls/Personal Protection Engineering ControlsProvide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Personal ProtectionSafety glasses. Lab coat. Gloves. Respiratory protection is not necessary for normal handling. Adequate general (room) ventilation or local exhaust (fume hood) is sufficient. Use a vapor respirator under conditions where exposure to the substance is apparent (e.g. generation of high concentrations of mist or vapor, inadequate ventilation, development of respiratory tract irritation), and engineering controls are not feasible. Be sure to use an approved/certified respirator or equivalent. Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a a Large Spillspecialist BEFORE handling this product. Exposure LimitsNot available. Section 9. Physical and Chemical Properties Physical state and appearance Liquid.OdorOdorless. Not available. Taste Molecular WeightNot applicable. Green. Bluish-Green. Clear (Dark.) Color pH (1% soln/water)Not available. Boiling Point>104.44°C (220°F) Melting PointNot available. Critical TemperatureNot available. Specific GravityNot available. Not applicable. Vapor Pressure Vapor DensityNot available. Not available. Volatility Odor ThresholdNot available. Water/Oil Dist. Coeff.Not available. Ionicity (in Water)Not available. Dispersion PropertiesNot available. SolubilitySoluble in cold water. Section 10. Stability and Reactivity Data StabilityThe product is stable. Instability TemperatureNot available. Conditions of InstabilityIncompatible materials Incompatibility with various Reactive with oxidizing agents. substances Nickel Sulfamate, Solution CorrosivityNon-corrosive in presence of glass. Special Remarks onNot available. Reactivity Special Remarks onNot available. Corrosivity PolymerizationWill not occur. Section 11. Toxicological Information Routes of EntrySkin contact. Eye contact. Toxicity to AnimalsLD50: Not available. LC50: Not available. Chronic Effects on Humans Not available. Other Toxic Effects onSlightly hazardous in case of skin contact (irritant), of ingestion, of inhalation. Humans Special Remarks onNot available. Toxicity to Animals Special Remarks onMay cause cancer (Nickel Sulfamate) Chronic Effects on Humans Special Remarks on otherAcute Potential Health Effects: Toxic Effects on HumansSkin: Can cause skin irritation. Eyes: Can cause eye irritation. Inhalaiton: May cause respiratory tract irritation. Ingestion: May be harmful if swallowed. Chronic Potential Health Effects: Skin: Prolonged or repeated skin contact may cause allergic skin reaction (allergic contact dermatitis). Section 12. Ecological Information EcotoxicityNot available. BOD5 and CODNot available. Products of BiodegradationPossibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the ProductsThe products of degradation are less toxic than the product itself. of Biodegradation Not available. Special Remarks on the Products of Biodegradation Section 13. Disposal Considerations Waste must be disposed of in accordance with federal, state and local environmental Waste Disposal control regulations. Nickel Sulfamate, Solution Section 14. Transport Information DOT ClassificationNot a DOT controlled material (United States). IdentificationNot applicable. Not applicable. Special Provisions for Transport DOT (Pictograms) Section 15. Other Regulatory Information and Pictograms California prop. 65: This product contains the following ingredients for which the State of California has found to Federal and State cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: Nickel Regulations sulfamate (listed as Nickel compounds) California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Nickel sulfamate (Listed as Nickel compounds) SARA 313 toxic chemical notification and release reporting: Nickel sulfamate (Listed as Nickel compounds) California prop. 65: This product contains the following ingredients for which the State of California has found California Proposition 65to cause cancer which would require a warning under the statute: Nickel sulfamate (Listed as Nickel Warningscompounds) California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. Other RegulationsFor Nickel Sulfamate (CAS no. 13770-89-3): EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No. 237-396-1). Canada: Listed on Canadian Domestic Substance List (DSL). China: Not listed on National Inventory. Japan: Listed on National Inventory (ENCS). Korea: Listed on National Inventory (KECI). Philippines: Listed on National Inventory (PICCS). Australia: Listed on AICS. Other ClassificationsWHMIS (Canada)CLASS D-2A: Material causing other toxic effects (VERY TOXIC). Class D-2B: Material causing other toxic effects (TOXIC). DSCL (EEC)R22- Harmful if swallowed.S26- In case of contact with eyes, rinse R40- Limited evidence of aimmediately with plenty of water and seek carcinogenic effect.medical advice. R43- May cause sensitization by skinS28- After contact with skin, wash immediately contact.with plenty of water. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. S46- If swallowed, seek medical advice immediately and show this container or label. Health Hazard HMIS (U.S.A.)1 National Fire Protection 0 Flammability 0 Association (U.S.A.) Fire Hazard 1 0 Reactivity Health Reactivity 0 Specific hazard Personal Protection E WHMIS (Canada) (Pictograms) Nickel Sulfamate, Solution DSCL (Europe) (Pictograms) TDG (Canada) (Pictograms) ADR (Europe) (Pictograms) Protective Equipment Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. SECTION 16 - ADDITIONAL INFORMATION N/A |
|
毒理学数据: 1、急性毒性： 主要的刺激性影响： 在皮肤上面：可能引起发炎； 在眼睛上面：可能引起发炎; 2、致敏作用：通过吸入可能造成敏化作用，通过皮肤接触可能造成敏化作用。 生态学数据: 对水体是极其有害的，即使小量产品也不能接触地下水，水道或污水系统, 若无政府许可，勿将材料排入周围环境
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
|
| 危害码 (欧洲) | F,T,T+ |
|---|---|
| 风险声明 (欧洲) | R10:Flammable. R15:Contact with water liberates extremely flammable gases. R20:Harmful by inhalation. R24/25:Toxic in contact with skin and if swallowed . R36/38:Irritating to eyes and skin . R44:Risk of explosion if heated under confinement. R36/37/38:Irr |
| 安全声明 (欧洲) | S26-S36/37-S43-S45-S36/37/39-S28A |
| 危险品运输编码 | UN 1992 3/PG 2 |
| WGK德国 | 2 |
| RTECS号 | US3675000 |
| 包装等级 | II |
| 危险类别 | 4.3 |
| 海关编码 | 2922499990 |
1.合成法将氨基磺酸与氢氧化镍反应生成氨基磺酸镍，经浓缩、结晶、离心分离，制得氨基磺酸镍成品。
| 海关编码 | 2922499990 |
|---|---|
| 中文概述 | 2922499990 其他氨基酸及其酯及它们的盐（含有一种以上含氧基的除外）. 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装 |
| 监管条件 | A.入境货物通关单 B.出境货物通关单 |
| 检验检疫 | P.进境动植物、动植物产品检疫 Q.出境动植物、动植物产品检疫 R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验 |
| Summary | HS:2922499990 other amino-acids, other than those containing more than one kind of oxygen function, and their esters; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0% |