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用作催化剂，也用于镍盐的制造
| 中文名 | 碳酸镍(II)水合物 |
|---|---|
| 英文名 | Nickel(II) carbonate, basic hydrate |
| 中文别名 | 碳酸镍,碱性 |
| 英文别名 |
nickelous carbonate hydroxide tetrahydrate
MFCD00150262 |
| 沸点 | 333.6ºC at 760mmHg |
|---|---|
| 分子式 | CH6Ni3O8 |
| 分子量 | 322.13400 |
| 闪点 | 169.8ºC |
| 精确质量 | 319.81200 |
| PSA | 153.34000 |
| 储存条件 | 密封、阴凉、干燥保存 |
| 稳定性 | 常规情况下不会分解，没有危险反应 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:5 3.氢键受体数量:8 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积68.2 7.重原子数量:10 8.表面电荷:-1 9.复杂度:18.8 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:7 |
| 更多 | 1. 性状：未确定 2. 密度（g/mL,20 ºC）：未确定 3. 相对蒸汽密度（g/mL,空气=1）： 未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC）：未确定 6. 沸点（ºC,16mm hg）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）： 未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）： 未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
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Section 1: Product Identification Chemical Name:Nickel (II) carbonate, basic hydrate CAS Registry Number:39380-74-0 Formula:NiCO3.2Ni(OH)2.XH2O EINECS Number:none Chemical Family:metal carbonate Synonym:Carbonic acid, nickel salt
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound39380-74-0100%0.2mg/m3 (as Ni1mg/m3 (as insol Ni) Section 3: Hazards Identification Emergency Overview:May cause intestinal disorders, convulsions, and asphyxia. May cause cancer. Primary Routes of Exposure:Ingestion, inhalation Eye Contact:May cause slight to mild irritation of the eyes. Skin Contact:May cause slight to mild irritation of the skin. Prolonged contact with nickel salts may lead to dermatitis. Inhalation:May be irritating to the nose, mucous membranes and respiratory tract. Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions. May be irritating to skin, eyes and respiratory tract, causing intestinal disorders, convulsions, asphyxia, Acute Health Affects: sensitization dermatitis, allergic asthma, and pneumonitis Long term exposure to nickel and nickel compounds may lead to skin irritation and dermatitis. May cause Chronic Health Affects: cancer. NTP:Yes IARC:Yes OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:none required If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andNone Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up. SECTION 7: Handling and Storage Handling and Storage:Store material in a tightly sealed bottle away from moisture. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and protective clothing. Ventilation:If possible, handle the material in an efficient fume hood. In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a Respirator: Respirator Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:green pwdr. Molecular Weight:320.16 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:Strong acids Incompatibility:Mineral acids Decomposition Products:none SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:Carcinogen (as Ni) Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound: see category code N495 for reporting Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 对水是稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统，若无政府许可，勿将材料排入周围环境。
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| 危害码 (欧洲) | Xn,N |
|---|---|
| 风险声明 (欧洲) | R22 |
| 安全声明 (欧洲) | S22;S60;S61;S36/S37 |
| 危险品运输编码 | UN 3077 9/PG 3 |